Results 21 to 30 of about 925,488 (170)

Luminescence Vapochromism of a Cu(I)/Na Phosphane Iodide Assembly Based on a Secondary‐Sphere Sodium Response

open access: yesAngewandte Chemie, EarlyView.
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen   +10 more
wiley   +2 more sources

Self-Assembly Heterometallic Cu-Ln Complexes: Synthesis, Crystal Structures and Magnetic Characterization

open access: yesCrystals, 2023
Using N2O4 donor symmetric ligand H2L and dca co-ligand, two new isostructural dinuclear CuII–LnIII complexes [Cu(Cl)(L)Ln(NO3)(CH3OH)(H2O)(dca)] [Ln=Ho (1CuHo), Gd (2CuGd)] [H2L = 6,6′-((1E,1′E)-(ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene ...
Shaoliang Zhang   +5 more
doaj   +1 more source

Synthesis of Functional Metallosupramolecular Complexes [PDF]

open access: yes
This thesis describes three areas of research which involve preparation of novel pyridyl-thiazole-containing ligands and the formation of their complexes with transition metal ions.
Cox, Nicola Michelle
core   +3 more sources

Dual d–p hybridization in Ternary PtGaGe Enables Concurrent Activity and Stability Enhancement for Alkaline Oxygen Reduction

open access: yesAngewandte Chemie, EarlyView.
A unique dual d–p orbital hybridization strategy was established in a ternary PtGaGe alloy catalyst to overcome the longstanding activity–stability trade‐off in oxygen reduction reaction (ORR). Synergistic hybridization between Ga/Ge p orbitals and Pt d orbitals modulates the Pt electronic structure, optimizes oxygen intermediates adsorption, and ...
Qian Zhang   +8 more
wiley   +2 more sources

New Cyanido-Bridged Heterometallic 3d-4f 1D Coordination Polymers: Synthesis, Crystal Structures and Magnetic Properties

open access: yesMagnetochemistry, 2021
Three new 1D cyanido-bridged 3d-4f coordination polymers, {[Gd(L)(H2O)2Fe(CN)6]·H2O}n (1GdFe), {[Dy(L)(H2O)2Fe(CN)6]·3H2O}n (2DyFe), and {[Dy(L)(H2O)2Co(CN)6]·H2O}n (3DyCo), were assembled following the building-block approach (L = pentadentate bis ...
Diana Dragancea   +3 more
doaj   +1 more source

Chiral, Heterometallic Lanthanide–Transition Metal Complexes by Design

open access: yesInorganics, 2018
Achieving control over coordination geometries in lanthanide complexes remains a challenge to the coordination chemist. This is particularly the case in the field of molecule-based magnetism, where barriers for magnetic relaxation processes as well as ...
Anders Øwre   +5 more
doaj   +1 more source

Synthesis, Characterization and Antitumor Mechanism Investigation of Heterometallic Ru(Ⅱ)-Re(Ⅰ) Complexes

open access: yesFrontiers in Chemistry, 2022
The development of heteronuclear metal complexes as potent anticancer agents has received increasing attention in recent years. In this study, two new heteronuclear Ru(Ⅱ)-Re(Ⅰ) metal complexes, [Ru(bpy)2LRe(CO)3(DIP)](PF6)3 and [Ru(phen)2LRe(CO)3(DIP ...
Xiurong Ma   +5 more
doaj   +1 more source

Tuning the emission of cationic iridium (III) complexes towards the red through methoxy substitution of the cyclometalating ligand [PDF]

open access: yes, 2015
EZ-C acknowledges CFI (Canadian Foundation for Innovation), NSERC (the Natural Sciences and Engineering Research Council of Canada), FQRNT (Le Fonds québécois de la recherche sur la nature et les technologies) and the University of St Andrews for ...
Samuel, Ifor David William   +5 more
core   +1 more source

Application of the Heptacyanidorhenate(IV) as a Metalloligand in the Design of Molecular Magnets

open access: yesMagnetochemistry, 2022
This review is devoted to an analysis of currently known heterometallic molecular magnets based on an orbitally degenerate 5d metalloligand, [ReIV(CN)7]3−.
Kira E. Vostrikova
doaj   +1 more source

Mononuclear Transition Metal Cymantrenecarboxylates as Precursors for Spinel-Type Manganites

open access: yesMolecules, 2022
Novel mononuclear cymantrenecarboxylate complexes of transition metals, [Co(H2O)6](CymCO2)2·4H2O (Cym = (η5-C5H4)Mn(CO)3) (1), [Ni(H2O)6](CymCO2)2·4H2O (2), [Zn(H2O)6](CymCO2)2·4H2O (3), [Co(CymCO2)2(imz)2] (imz = imidazole, 4), [Co(CymCO2)2(bpy)2]·2PhMe
Pavel S. Koroteev   +4 more
doaj   +1 more source

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