Results 81 to 90 of about 5,186,208 (171)

Adsorption‐Programmed Transformation of a Two‐Dimensional Cu–Imidazolate Framework into Mn‐Integrated Catalytic Nanonetwork

open access: yesSmall, EarlyView.
A freeze‐dried copper‐based metal‐organic framework removes more than 95% of manganese from water. Capturing the metal reorganizes the framework, giving the used adsorbent a second life as a reusable catalyst that produces valuable ester products in yields up to 84%.
Prathmesh Bhadane   +7 more
wiley   +1 more source

Mixed-Ligand Approach to Design of Heterometallic Single-Source Precursors with Discrete Molecular Structure

open access: yes, 2016
Heterometallic single-source precursors for the Pb/Fe = 1:1 oxide materials, PbFe­(β-dik)4 (β-dik = hexafluoroacetylacetonate (hfac, 1), acetylacetonate (acac, 2), and trifluoroacetylacetonate (tfac, 4)), have been isolated by three different solid ...
Haitao Zhang (47756)   +4 more
core   +2 more sources

Heptanuclear iron complex as a potential contrast agent for MRI

open access: yesMagnetic Resonance Letters
A heptanuclear complex of the composition [Fe(II)(CN)6{Fe(III)](L)}6](SCN)2, where L = dianion N,N-bis(1-hydroxy-2-benzylidene)-1,7-diamino-4-azageptane has been studied as a potential contrast agent for magnetic resonance imaging.
Ekaterina E. Batueva   +4 more
doaj   +1 more source

Polarity‐engineered Sn‐Ti cluster photoresists for sub‐10‐nm high‐resolution lithography

open access: yesSmart Molecules, EarlyView.
Enhancing the polarity of clusters can optimize their patterning performance; inspired by this strategy, we designed polarity‐enhanced Sn‐Ti oxo clusters via ligand engineering. The optimal TS‐3 with exposure‐induced polarity switch achieves 8 nm patterning in lithography and achieves simultaneous improvement in resolution and patterning performance ...
Daohan Wang   +10 more
wiley   +1 more source

Novel Heterometallic Lanthanide Silsesquioxane

open access: yes, 2016
Novel Heterometallic Lanthanide ...
Alexander Steiner (2234449)   +2 more
core   +1 more source

Stepwise Synthesis, Hydrogen-Bonded Supramolecular Structure, and Magnetic Property of a Co–Mn Heterodinuclear Complex

open access: yesMagnetochemistry, 2019
A cobalt(III)⁻manganese(II) heterometallic dinuclear complex, [MnII{CoIII(µ-Himn)3}Cl2(CH3OH)], was prepared by a metalloligand approach.
Ryoji Mitsuhashi   +2 more
doaj   +1 more source

Advances in research on layered double hydroxides for biomedical applications

open access: yesSmart Molecules, EarlyView.
Layered double hydroxides (LDHs) are pH‐responsive nanomaterials with broad biomedical applications. This review summarizes LDH synthesis methods and compares their advantages. It highlights LDHs' progress in cancer therapy, including chemo‐photothermal, chemo‐immunotherapy, and photodynamic‐immunotherapy combinations and their potential in bone repair.
Xinhui Yang   +13 more
wiley   +1 more source

Group 13 Aminopyridinato Complexes and Co─Al Heterobimetallics: Impact of Ligand Substituent and Metal Exchange on Thermal Behavior

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
A family of monometallic aluminum and gallium complexes supported by simple aminopyridinato ligands was synthesized and fully characterized by NMR spectroscopy and single‐crystal X‐ray diffraction. In addition, two Co─Al heterobimetallic complexes were synthesized and structurally characterized.
Pauline B. Lemp   +6 more
wiley   +1 more source

SYNTHESIS AND CRYSTAL-STRUCTURE OF A PENTANUCLEAR HETEROMETALLIC ACETYLIDE COMPLEX CP2MO2RU3(CO)10(C=CPH)2

open access: yes, 2011
[[abstract]]The pentanuclear heterometallic acetylide complex Cp2Mo2Ru3(CO)10(CCPh)2 (3) was prepared by the reaction of the metal acetylide CpMo(CO)3CCPh with Ru3(CO)12. This complex was characterized by spectroscopic methods and by X-ray single-crystal
HWANG DK;YUN C;PENG SM;LEE GH
core   +1 more source

Crystal structure of a Pd4 carbonyl triphenylphosphane cluster [Pd4(CO)5(PPh3)4]·2C4H8O, comparing solvates

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
Attempts to synthesize Au–Pd heterometallic compounds from homonuclear palladium or gold complexes, [Pd(PtBu2)2] and [Au(PPh3)Cl] in a tetrahydrofuran (THF) solution under a CO atmosphere resulted in a homonuclear Pd cluster, namely pentakis(μ-carbonyl ...
Koen Robeyns   +4 more
doaj   +1 more source

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