Results 231 to 240 of about 153,197 (305)

Electrochemical Design of Atomically Conformal Ga2O3 Buffer Layers via Cu2O‐Catalyzed Nitrate Reduction Reaction for Efficient Cu2O Photocathodes

Carbon Energy, EarlyView.
Cu2O catalyzes nitrate reduction to locally generate OH− at the electrode surface, enabling the first uniform electrochemical deposition of Ga2O3. The Cu2O/Ga2O3‐based photocathodes achieve onset potentials above 1 VRHE, 3.8% solar‐to‐hydrogen efficiency, and stable operation for over 60 h in all‐inorganic tandem PEC devices.
Ji Hoon Choi, Hak Hyeon Lee, Ji Hye Jeong, Dong Su Kim, Kun Woong Lee, Won Seok Yang, Hyung Koun Cho   +6 more
wiley   +1 more source

Formation and Characterization of Insoluble Anthocyanins‐λ‐carrageenan Biopolyelectrolyte Complexes: Structural Morphology, Thermal Stability, and Release Dynamics

ChemFoodChem, EarlyView.
Insoluble biopolyelectrolyte complexes formed between blackberry anthocyanins and λ‐carrageenan are investigated. Optimal complexation occurs at low carrageenan ratios and acidic pH, producing porous hydrogel‐like structures with enhanced thermal stability.
Tomás Garrido, Ana Rita Pereira, Hiléia K. S. Souza, Nuno Mateus, Victor de Freitas, Ana Fernandes   +5 more
wiley   +1 more source

Room‐Temperature Helix‐to‐Disc Conversion of Thia[6]helicene S,S‐Dioxides to Coronene via In Situ Phenoxide Anion Generation

Chemistry – A European Journal, EarlyView.
In situ phenoxide formation at the benzene terminus triggers room‐temperature conversion of thia[6]helicene S,S‐dioxides to coronene. The solubility contrast drives product precipitation, enabling isolation by simple filtration. This pericyclic annulation between the helical termini provides direct access to coronene‐type planar architectures ...
Kaito Seino, Takashi Murase
wiley   +1 more source

Pyropheophytin a accompanies pheophytin a in darkened light grown cells of Euglena [PDF]

, 1981
Rüdiger, W., Scheer, Hugo, Schiff, J. A., Schoch, S., Siegelmann, H. W.   +4 more
core  

Amine‐Triggered Azabenz‐Annulation of Cyclic Secondary Amine‐Functionalized Perylene Diimides for Dual‐Mode Sensing

Chemistry – A European Journal, EarlyView.
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park, Alejandro J. Cuellar de Lucio, Gregory C. Welch   +2 more
wiley   +1 more source

Three‐Step Synthesis Toward Fluorene‐Based Non‐Fused‐Ring Acceptors for Organic Solar Cells

Chemistry – A European Journal, EarlyView.
Applying a simple three step synthesis strategy leads to two fluorene‐based non‐fused‐ring electron acceptors, FHM‐Cl and FHM‐F for organic solar cells. The chlorinated variant delivers markedly higher efficiency due to broader light harvesting and favorable molecular packing, resulting in improved charge transport and reduced recombination losses ...
Virginia Lafranconi, Suman Mallick, Lisa Nauta, Lisa Inzko, Julia Hönigsberger, Danijel Babic, Bettina Schlemmer, Daniele Padula, Heinz Amenitsch, Thomas Rath, Gregor Trimmel   +10 more
wiley   +1 more source

Multifunctional Heterocyclic Scaffolds for Hybrid Lewis Acid/Lewis Base Catalysis of Carbon–Carbon Bond Formation [PDF]

, 2016
Benoit, Adam R., Dockendorff, Chris, Huff, Raechel, Lindeman, Sergey, Meyle, Elisia, Porter, Jacob D., Wiedenhoeft, Dennis, Wu, Yibiao, Yeung, Teresa H.W.   +8 more
core   +1 more source

When Light Challenges Heat: Mechanistic Insights Into a Reaction Competing With Cadogan Cyclisation in Nitro‐Perylenediimides

Chemistry – A European Journal, EarlyView.
Visible‐light irradiation of nitro‐perylenediimide in the presence of triphenylphosphine reveals an unexpected pathway competing with the classical Cadogan cyclization. Mechanistic investigations uncover the rapid and selective formation of bay‐functionalized 1‐iminophosphorane‐12‐hydroxy perylenediimide derivatives.
Manuel Pedrón Laserna, Ilaria Ciofini, Piétrick Hudhomme   +2 more
wiley   +1 more source

Green Electrochromic Film Formation via Phenylcarbazole Polymerization in Ionic Liquids

Chemistry – A European Journal, EarlyView.
The scheme depicts the three‐step electropolymerization of two electrochromic polycarbazole derivatives, 4‐(9H‐carbazol‐9‐yl)phenol and 4‐(3‐methoxy‐9H‐carbazol‐9‐yl)phenol, performed at constant potential using the green ionic liquid BMIM TFSI. This medium enables controlled polymer growth and enhances electrochromic performance, yielding robust and ...
Carolina Gascó, Sara Santiago, Rosa Maria Sebastián, Gonzalo Guirado   +3 more
wiley   +1 more source

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal, Martha Eugenia Albores Velasco, René O. Vargas, Rubén Mil‐Martínez   +3 more
wiley   +1 more source