Results 191 to 200 of about 19,472 (303)

Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee   +3 more
wiley   +1 more source

Decoupling Chemical and Mechanical Contributions to Capacity Fading in Ni‐Rich Cathodes for Sulfide‐Based All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Ni‐rich cathodes in sulfide‐based ASSBs undergo intertwined (electro)chemical and mechanical degradation. Here, a new diagnostic framework is presented to decouple each contribution by partitioning capacity fading into charge and discharge fading.
Jangwhan Seok   +12 more
wiley   +1 more source

Universal Oxychlorination Strategy in Halide Solid Electrolytes for All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A WO2Cl2‐driven oxychlorination strategy enables bulk oxygen incorporation into close‐packed LixMCl6 (M = Zr, Y, Er, In) halide lattices. Oxygen is selectively anchored by W6+ as lattice‐integrated [WO2Cl4]2− units, regulating the anionic framework, diversifying Li coordination, and weakening Li–Cl interactions.
Jae‐Seung Kim   +13 more
wiley   +1 more source

Ultra‐Low‐Strain Calcium and Magnesium Ion Storage Enabled by Tunnel‐Structured MoO3 Positive Electrode

open access: yesAdvanced Energy Materials, EarlyView.
A hexagonal tunnel‐structured MoO3 is nanoparticulated via hydrothermal synthesis followed by ball‐milling. As a positive electrode in Ca and Mg batteries, it delivers superior capacity and structural reversibility, enabling divalent cation intercalation with minimal lattice distortion and no phase transitions.
Reona Iimura   +10 more
wiley   +1 more source

Unveiling the High‐Voltage Reactivity and Gas Evolution With Aluminum‐Based Chloride and Oxychloride Catholytes in Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The work examines the electrochemical and interfacial behaviors of crystalline NaAlCl4 and amorphous Na–Al–oxychloride solid electrolytes with NaNi0.5Mn0.5O2 cathodes. Operando gas evolution and ToF‐SIMS analyses highlight that pure chloride solid electrolytes offer greater interfacial stability and safety compared to the oxychloride solid electrolytes
Erick Ruoff   +2 more
wiley   +1 more source

Investigation Into the Electrochemical Performance of Micron‐ and Nanosized Tin in Diglyme and Carbonate Electrolytes in Sodium Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This study compares Sn particles of different sizes in NIBs using carbonate‐ and diglyme‐based electrolytes. Diglyme electrolytes enable stable cycling despite large volume changes, while carbonate electrolytes degrade rapidly, especially with nanoparticles.
Chinnasamy Murugesan   +4 more
wiley   +1 more source

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