Results 101 to 110 of about 2,760 (255)
Chemistry – A European Journal, EarlyView.Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.ABSTRACT Hexanuclear cyclic Gd(III) coordination compounds are promising candidates for magnetic and magnetocaloric applications, yet systematic series remain rare due to synthetic challenges. We report the synthesis and characterization of five new complexes with the general formula [Gd(H3bt)(carboxylate)]6, employing four different carboxylate ...
Ondřej František Fellner +7 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.This study reports six new copper(I) complexes with unusual coordination and strong anticancer activity against a panel of human cancer cell lines derived from different solid tumors. The most active compounds outperform cisplatin, even in resistant cells, by inhibiting protein disulfide isomerase and inducing redox stress that triggers non‐apoptotic ...
Vo Quang Huy Phan +9 more
wiley +1 more source
A hidden Markov model and reinforcement learning‐based strategy for fault‐tolerant control
The Canadian Journal of Chemical Engineering, EarlyView.Abstract This study introduces a data‐driven control strategy integrating hidden Markov models (HMM) and reinforcement learning (RL) to achieve resilient, fault‐tolerant operation against persistent disturbances in nonlinear chemical processes. Called hidden Markov model and reinforcement learning (HMMRL), this strategy is evaluated in two case studies
Tamera Leitao +2 more
wiley +1 more source
Corporate Social Responsibility and Environmental Management, EarlyView.ABSTRACT This study explores the potential influence of key components of the board of directors' architecture on ESG outcomes. Specifically, we focus on the effects of demographic components (gender and cultural diversity), structural and compositional factors (size, CEO‐Chair separation, and the presence of independent/non‐executive directors), and ...
Jorge Ochaita‐Gonzalez +3 more
wiley +1 more source
Deep Underground Science and Engineering, EarlyView.The present manuscript explored the effects of joint configurations on the cyclic shear behavior of intermittent joints for the first time. The cyclic shear response, shear strength degradation, dilation characteristics evolution, frictional property, fractal dimension, and dissipative energy were further analyzed during shear cycles, which is crucial ...
Bin Wang +3 more
wiley +1 more source
Gold(I) Phosphine/Phosphido‐Borohydride Complexes
European Journal of Inorganic Chemistry, EarlyView.Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
wiley +1 more source
Synthesis, Crystal Structure, and Optoelectronic Properties of [(n‐/tert‐C4H9)S(CH3)2]PbI3
European Journal of Inorganic Chemistry, EarlyView.Reaction of two isomers of butyldimethylsulfonium cation with PbI2 using solid‐state and solution methods yielded the corresponding organic/inorganic hybrid compounds with high humidity tolerance and 1D crystal structures of [n‐C4H9S(CH3)2]PbI3 and [tert‐C4H9S(CH3)2]PbI3.
Ioannis Koutsoumpogeras +4 more
wiley +1 more source
On the Verge of Exclusion: The Unique Psychological Profile of the Threat of Social Exclusion
European Journal of Social Psychology, EarlyView.ABSTRACT Past research, often using Cyberball—an online ball‐tossing game with two or more preprogrammed players—showed that being socially excluded produces various negative emotions and lower need satisfaction. However, in everyday life, people may experience the threat of social exclusion more frequently than actual exclusion. Across two experiments
Tiara R. Widiastuti +3 more
wiley +1 more source
How Changing Narratives About the Future Shape Policymaking for the Long Term
European Policy Analysis, EarlyView.ABSTRACT How can we explain decisions by governments to engage in policy investments—accepting short‐term costs in return for anticipated gains in the longer term—after previously sustaining the status quo? Our article examines the role of narratives in changing expectations about the future as a key driver of intertemporal policymaking. In light of an
Pieter Tuytens, Charlotte Haberstroh
wiley +1 more source