Results 131 to 140 of about 49,207 (274)

Why Is the Mechanism Underlying the Chiral‐Induced Selectivity Effect Still Challenging?

open access: yesAdvanced Materials, EarlyView.
The chiral‐induced spin selectivity (CISS) effect is observed in many experimental configurations and for different materials. However, there are theoretical challenges in attempting to explain those results. A qualitative framework for explaining all the results is presented.
Ron Naaman, Yossi Paltiel
wiley   +1 more source

White‐Light Emission in Zeolitic Imidazolate Framework Glasses

open access: yesAdvanced Materials, EarlyView.
Broadband blue emission is discovered in ZIF‐62 through vitrification and hot‐pressing. This emission is significantly enhanced and redshifted when the ZIF‐62 glass is annealed above the critical temperature (1.07Tg), being attributed to an enhancement of ligand‐to‐ligand charge transfer.
Zhencai Li   +19 more
wiley   +1 more source

Engineering Small HOMO–LUMO Gaps in Polycyclic Aromatic Hydrocarbons with Topologically Protected States [PDF]

open access: hybrid
Kaitlin Slicker   +7 more
openalex   +1 more source

Highly‐Emissive Organic Photovoltaics Approaching Theoretical Limit Voltage and Enabling Multifunctional Energy‐Harvesting Displays

open access: yesAdvanced Materials, EarlyView.
A highly‐emissive organic photovoltaic employs donor–acceptor pairs with alternately localized frontier molecular orbitals, preserving high triplet energies and small reorganization energies to suppress non‐radiative recombination. As a result, it exhibits a high open‐circuit voltage approaching the Shockley–Queisser limit and a high ...
Qing‐Jun Shui   +7 more
wiley   +1 more source

Toward the Synthetic Control of the HOMO−LUMO Gap in Binuclear Systems: Insights from Density Functional Calculations

open access: green, 2010
Alvaro Muñoz‐Castro   +5 more
openalex   +2 more sources

Inert Catalytic Sites Unlocked by Micropollutants for Rapid Water Decontamination with Near‐Complete Chemical Utilization

open access: yesAdvanced Materials, EarlyView.
Micropollutants can act as molecular triggers that activate a newly designed and chemically inert Fenton‐like PKU‐24 catalyst for on‐demand singlet oxygen generation from peroxymonosulfate (PMS), enabling nearly complete peroxide utilization and selective micropollutant removal from complex real‐world wastewater.
Yu‐Hang Li   +7 more
wiley   +1 more source

Light‐Controlled Exposure of Cancer Cells to Reactive Oxygen Species Using Organic Semiconductor Thin Films

open access: yesAdvanced Materials Interfaces, EarlyView.
Spin‐coated films of the conjugated polymer F8T2 (poly (9,9‐dioctylfluorene‐alt‐bithiophene)) generate superoxide at the film‐medium interface, enabling precise delivery of reactive oxygen species (ROS) as visible‐light “ROS patches.” Coated surfaces drive rapid, localised cytotoxicity in MCF7 cancer monolayers under white light, providing a reagent ...
Joe Kaye   +8 more
wiley   +1 more source

Engineering a Small HOMO–LUMO Gap and Intramolecular C−H Borylation by Diborene/Anthracene Orbital Intercalation

open access: green, 2017
Sunewang R. Wang   +12 more
openalex   +2 more sources

Exploring the Potential of Zero‐Dimensional Carbon Nanomaterials in Photoluminescent, Electrochemiluminescent and Electrochemical Sensors

open access: yesAdvanced Materials Interfaces, EarlyView.
Zero‐dimensional carbon nanomaterials are presented as multifunctional platforms linking structure, property, and sensing performance. Surface engineering and heteroatom doping modulate electron‐transfer and luminescent behavior, enabling electrochemical, photoluminescent, and electrochemiluminescent detection. Fundamental design principles, analytical
Gustavo Martins   +8 more
wiley   +1 more source

Electronic Structure Modulation Induced by Asymmetric Cu─Ni Centers in a π‐Conjugated Triazine MOF

open access: yesAdvanced Materials Interfaces, EarlyView.
A π‐conjugated H3TATB‐based asymmetric bimetallic CuNi‐MOF was developed as an efficient electrocatalyst for alkaline hydrogen evolution. Benefiting from synergistic Cu–Ni interactions, enhanced charge transfer, and stabilized active sites, CuNi‐MOF delivers superior HER performance with low overpotential, improved kinetics, and 24 h durability.
Alamgir   +7 more
wiley   +1 more source

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