Results 141 to 150 of about 108,077 (187)
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Titanium‐Mediated Oxidative Arylation of Homoallylic Alcohols
Angewandte Chemie International Edition, 2011The addition of aryl groups to unactivated olefins represents a direct approach to C!C bond construction. Pd-catalyzed coupling of aryl halides with alkenes, the Heck reaction, offers a viable approach to arylation. However, terminal unactivated olefins often display low reactivity in Heck reactions and can yield mixtures of styrenes and allyl arenes ...
Kathleen S, Lee, Joseph M, Ready
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Synthesis of Homoallylic Alcohols from Ketones in Water.
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Jun Wang, Gu Yuan
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Enantioselective hydrogenation of allylic and homoallylic alcohols
Journal of the American Chemical Society, 1987Hydrogenation enantioselective en particulier du geraniol et du nerol catalysee par des complexes dicarboxylato du ruthenium(II) contenant des coordinats bis-diarylphosphino-2,2' binaphtyles-1,1'
Hidemasa Takaya +7 more
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Addition of organocerium reagents to homoallyl alcohols
Tetrahedron Letters, 2001Abstract Alkylcerium reagents and hydride ions add to multiple bonds of homoallyl alcohols under mild conditions, leading to saturated alcohols in good yields.
BARTOLI G +5 more
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Synthesis of homoallylic alcohols in aqueous media
The Journal of Organic Chemistry, 1989The reaction of aldehydes or ketones with allyl halides/Zn takes place readily in aqueous NH{sub 4}Cl solution in the presence of C-18 silica as a solid organic cosolvent. This efficient and high-yield reaction parallels the Grignard reaction in terms of stereo- and regioselectivity.
Stephen R. Wilson, Maria E. Guazzaroni
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Radical cyclizations of bromo ketals from decalin homoallylic and bis-homoallylic alcohols
Tetrahedron Letters, 2001Abstract The radical cyclizations of bromo ketals derived from the Birch-alkylation products of α-tetralones are described. The carboncarbon bond formation proceeds in a regio- and stereoselective way. The intra- and intermolecular trapping behavior was also explored.
Guillermo R Labadie +2 more
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Diastereoselective Cycloadditions of Chiral Homoallylic Alcohols with Benzonitrile Oxide.
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Martin G. Kociolek, Chayanant Hongfa
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Copper‐Catalyzed Trifluoromethylation of Trisubstituted Allylic and Homoallylic Alcohols
Chemistry – A European Journal, 2015AbstractAn efficient copper‐catalyzed trifluoromethylation of trisubstituted allylic and homoallylic alcohols with Togni’s reagent has been developed. This strategy, accompanied by a double‐bond migration, leads to various branched CF3‐substituted alcohols by using readily available trisubstituted cyclic/acyclic alcohols as substrates.
Jian, Lei +6 more
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General and Practical Approach to the Syntheses of Linear Homoallylic Alcohols
ChemInform, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
Hin-Soon Cheng, Teck-Peng Loh
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Chemistry Letters, 1993
Abstract Whereas platinum-catalyzed hydrogermylation of 3-hexenoxydipropylgermane provided five-membered ring product (5-propyl-1-germa-2-oxacyclopentane) as a main product, triethylborane induced radical cyclization gave six-membered ring product (6-ethyl-1-germa-2-oxacyclohexane) selectively.
Masahiko Taniguchi +2 more
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Abstract Whereas platinum-catalyzed hydrogermylation of 3-hexenoxydipropylgermane provided five-membered ring product (5-propyl-1-germa-2-oxacyclopentane) as a main product, triethylborane induced radical cyclization gave six-membered ring product (6-ethyl-1-germa-2-oxacyclohexane) selectively.
Masahiko Taniguchi +2 more
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