Total Syntheses of Sappanin-Based Natural Products Enabled by Pattern Recognition Analysis and Brominative Aromatization. [PDF]
Zhao WT, Liang JY, Wu YK.
europepmc +1 more source
DDQ-catalyzed oxidative α-allylation of isochromans under aerobic conditions. [PDF]
Lee S, Jung S, Hyeon S, Kim K, Min SJ.
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Scalable Total Synthesis of Bastimolide A Enabled by Asymmetric Allylborations Catalyzed by Chiral Brønsted Acids. [PDF]
Umemiya S +3 more
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Facile, general allylation of unactivated alkyl halides <i>via</i> electrochemically enabled radical-polar crossover. [PDF]
Chen H, Rueping M.
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DFT Calculation-Assisted Virtual Screening to Refine Chiral Phosphoric Acid-Catalyzed Allylboration Enabling Organocatalytic Synthesis of Tetrafibricin C21-C40 Fragment. [PDF]
Umemiya S, Hirata T, Terada M.
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Kinetics and Mechanisms of the Allyl + Allyl and Allyl + Propargyl Recombination Reactions
The Journal of Physical Chemistry A, 2011The kinetics and mechanisms of the self-reaction of allyl radicals and the cross-reaction between allyl and propargyl radicals were studied both experimentally and theoretically. The experiments were carried out over the temperature range 295-800 K and the pressure range 20-200 Torr (maintained by He or N(2)).
Akira, Matsugi +2 more
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Allylation of Epoxides with Allylic Indium Reagents.
ChemInform, 2004Allylindium sesquihalide reacts with epoxide to give homoallyl alcohol via a 1,2-shift reaction. In contrast, allylindate gives the ring-opening product without rearrangement.
Tsunehisa Hirashita +3 more
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Triflimide-catalyzed allyl–allyl cross-coupling: a metal-free allylic alkylation
Chemical Communications, 2012A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
Ding, Feiqing +3 more
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Telomerization Studies with Allyl Ethene Sulfonate and Allyl Allyl Sulfonate
Journal of Macromolecular Science: Part A - Chemistry, 1971Abstract Telomerization of allyl ethene sulfonate (AES) in the presence of butyl mercaptan yielded a mixture of two products: the first was a five-membered ring sultone containing a sulfide group and the second a five-membered ring sulfonium salt formed by reaction of the sultone of the Just product with its own sulfide function.
E. De Witte, E. J. Goethals
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