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Kinetics and Mechanisms of the Allyl + Allyl and Allyl + Propargyl Recombination Reactions

The Journal of Physical Chemistry A, 2011
The kinetics and mechanisms of the self-reaction of allyl radicals and the cross-reaction between allyl and propargyl radicals were studied both experimentally and theoretically. The experiments were carried out over the temperature range 295-800 K and the pressure range 20-200 Torr (maintained by He or N(2)).
Akira, Matsugi   +2 more
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Allylation of Epoxides with Allylic Indium Reagents.

ChemInform, 2004
Allylindium sesquihalide reacts with epoxide to give homoallyl alcohol via a 1,2-shift reaction. In contrast, allylindate gives the ring-opening product without rearrangement.
Tsunehisa Hirashita   +3 more
openaire   +1 more source

Triflimide-catalyzed allyl–allyl cross-coupling: a metal-free allylic alkylation

Chemical Communications, 2012
A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
Ding, Feiqing   +3 more
openaire   +3 more sources

Telomerization Studies with Allyl Ethene Sulfonate and Allyl Allyl Sulfonate

Journal of Macromolecular Science: Part A - Chemistry, 1971
Abstract Telomerization of allyl ethene sulfonate (AES) in the presence of butyl mercaptan yielded a mixture of two products: the first was a five-membered ring sultone containing a sulfide group and the second a five-membered ring sulfonium salt formed by reaction of the sultone of the Just product with its own sulfide function.
E. De Witte, E. J. Goethals
openaire   +1 more source

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