Results 41 to 50 of about 12,893 (216)
Frontiers in ChemistryThe Hosomi–Sakurai allylation reaction has been widely applied in the total synthesis of biologically active natural products, especially in synthesising complex polycyclic compounds containing multi-stereogenic centres since its discovery in 1976.
Justice Akwensi +3 more
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Protein Arginine Allylation and Subsequent Fluorophore Targeting
, 2013 Protein Arginine Allylation and Subsequent Fluorophore ...
Pan, Yanbo +6 more
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Platinum-Catalyzed Allylation of 2,3-Disubstituted Indoles with Allylic Acetates
Molecules, 2017 Given the importance of heterocycle indole derivatives, much effort has been directed toward the development of methods for functionalization of the indole nucleus at N1 and C3 sites.
Bai-Jing Peng +2 more
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(E)-2-(1,3-Diphenylallyl)-3,5-dimethoxyphenol
Molbank, 2023 The synthesis of (E)-2-(1,3-diphenylallyl)-3,5-dimethoxyphenol is described by means of the reaction of 3,5-dimethoxyphenol with (E)-1,3-diphenylprop-2-en-1-ol in 1,1,1,3,3,3-hexafluoroispropanol (HFIP), which acts as a solvent and reaction promoter. The
Lara Mollà-Guerola, Alejandro Baeza
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Molecules, 2019 The organo-catalyzed enantioselective benzylation reaction of α-trifluoromethoxy indanones afforded α-benzyl-α-trifluoromethoxy indanones with a tetrasubstituted stereogenic carbon center in excellent yield with moderate enantioselectivity
Yumeng Liang +3 more
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DFT Studies on the Allylation of Styrene Oxide Catalyzed by Indium Nanoparticles (InNPs)
Chemistry Proceedings, 2022 Allyl–indium species are known to smoothly react with electrophiles as epoxides. The intrinsic tension of these cyclic systems makes them very reactive starting materials, giving access to more complex products through regioselective ring-opening.
Lucía Rossi-Fernández +3 more
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Boron-Catalyzed, Diastereo- and Enantioselective Allylation of Ketones with Allenes [PDF]
, 2022 The diastereo- and enantioselective allylation of ketones remains a synthetic challenge, with transition metal catalysis offering the most applied methods. Here, a boron-catalyzed allylation of ketones with allenes is presented.
Willcox, Dominic R.; id_orcid +16 more
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Re2O7-catalyzed reaction of hemiacetals and aldehydes with O-, S-, and C-nucleophiles
Beilstein Journal of Organic Chemistry, 2013 Re(VII) oxides catalyze the acetalization, monoperoxyacetalization, monothioacetalization and allylation of hemiacetals. The reactions, which take place under mild conditions and at low catalyst loadings, can be conducted using hemiacetals, the ...
Wantanee Sittiwong +4 more
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Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
Molecules, 2016 The Pd-catalyzed direct alkylation of H-phosphinic acids and hypophosphorous acid with allylic/benzylic alcohols has been described previously. Here, the extension of this methodology to H-phosphinate esters is presented. The new reaction appears general,
Anthony Fers-Lidou +2 more
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Energetics of the Allyl Group [PDF]
The Journal of Organic Chemistry, 2007 Aiming to improve our understanding of the stability of radicals containing the allylic moiety, carbon-hydrogen bond dissociation enthalpies (BDEs) in propene, isobutene, 1-butene, (E)-2-butene, 3-metylbut-1-ene, (E)-2-pentene, (E)-1,3-pentadiene, 1,4-pentadiene, cyclohexene, 1,3-cyclohexadiene, and 1,4-cyclohexadiene have been determined by quantum ...
Filipe, Agapito +4 more
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