Results 51 to 60 of about 11,460 (224)
Regiospecific Decarboxylative Allylation of Nitriles
, 2016 Palladium-catalyzed decarboxylative α-allylation of nitriles readily occurs with use of Pd2(dba)3 and rac-BINAP. This catalyst mixture also allows the highly regiospecific α-allylation of nitriles in the presence of much more acidic α-protons.
Antonio Recio (1849078) +1 more
core +1 more source
New Radical Allylation Reaction
, 2016 New Radical Allylation ...
Béatrice Quiclet-Sire (2675125) +1 more
core +2 more sources
Energetics of the Allyl Group [PDF]
The Journal of Organic Chemistry, 2007 Aiming to improve our understanding of the stability of radicals containing the allylic moiety, carbon-hydrogen bond dissociation enthalpies (BDEs) in propene, isobutene, 1-butene, (E)-2-butene, 3-metylbut-1-ene, (E)-2-pentene, (E)-1,3-pentadiene, 1,4-pentadiene, cyclohexene, 1,3-cyclohexadiene, and 1,4-cyclohexadiene have been determined by quantum ...
Filipe, Agapito +4 more
openaire +2 more sources
Asymmetric organocatalytic synthesis of chiral homoallylic amines
Beilstein Journal of Organic ChemistryIn recent decades, the chiral allylation of imines emerged as a key methodology in the synthesis of alkaloids and natural products with 4-, 5- and 6-membered cyclic amine motifs.
Nikolay S. Kondratyev, Andrei V. Malkov
doaj +1 more source
Angewandte Chemie International Edition, EarlyView.Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang +1 more
wiley +1 more source
Origin of Protonation Side Products in Pd-Catalyzed Decarboxylative Allylation Reactions: Evidence for In Situ Modification of Triphenylphosphine Ligand [PDF]
, 2021 Palladium-catalyzed decarboxylative allylation (DcA) is a well-established method of carbon-carbon bond formation. This type of coupling is quite attractive, as the only byproduct is CO2.
Monica A., Gill +2 more
core +2 more sources
(E)-2-(1,3-Diphenylallyl)-3,5-dimethoxyphenol
Molbank, 2023 The synthesis of (E)-2-(1,3-diphenylallyl)-3,5-dimethoxyphenol is described by means of the reaction of 3,5-dimethoxyphenol with (E)-1,3-diphenylprop-2-en-1-ol in 1,1,1,3,3,3-hexafluoroispropanol (HFIP), which acts as a solvent and reaction promoter. The
Lara Mollà-Guerola, Alejandro Baeza
doaj +1 more source
Iridium Catalyzed Enantioselective Intermolecular Indole C2-Allylation [PDF]
, 2020 The enantioselective intermolecular C2-allylation of 3-substituted indoles is reported for the first time. This directing group-free approach relies on a chiral Ir-(P, olefin) complex and Mg(ClO4)2 Lewis acid catalyst system to promote allylic ...
Zheng, Chao +13 more
core +1 more source
Nature CommunicationsThe functionalized polycycle with densely contiguous tertiary stereocenters is a formidable challenge in synthesizing the parvistemoline family of Stemona alkaloids.
Xiao Liang +7 more
doaj +1 more source
Angewandte Chemie International Edition, EarlyView.Myxoglucamide A—a novel glycolipopeptide isolated from myxobacteria—was synthesized, and activity‐based protein profiling identified aldo‐keto reductase 1C3 (AKR1C3) as its main target in human cells. Structure‐activity relationship studies, together with biophysical characterization and X‐ray crystallography, elucidated the structural basis of AKR1C3 ...
Thomas Siemon +9 more
wiley +1 more source