Iodine-Catalyzed Prins Cyclization of Homoallylic Alcohols and Aldehydes [PDF]
Molecules, 2013 The iodine-catalyzed Prins cyclization of homoallylic alcohols and aldehydes was investigated under metal-free conditions and without additives. Anhydrous conditions and inert atmosphere are not required.
Luiz F. Silva +4 more
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Nickel-catalyzed arylative substitution of homoallylic alcohols. [PDF]
Chem Sci, 2022 Arylative substitutions of homoallylic alcohols with arylboron nucleophiles demonstrate the utility of unactivated alcohols as coupling partners in transition metal-catalyzed cross-coupling chemistry.
Tran HN +4 more
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Chiral Syn-1,3-diol Derivatives via a One-Pot Diastereoselective Carboxylation/ Bromocyclization of Homoallylic Alcohols [PDF]
iScience, 2018 Summary: Chiral syn-1,3-diols are fundamental structural motifs in many natural products and drugs. The traditional Narasaka-Prasad diastereoselective reduction from chiral β-hydroxyketones is an important process for the synthesis of these ...
Guanxin Huang +7 more
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Barbier-type anti-Diastereo- and Enantioselective Synthesis of β-Trimethylsilyl, Fluorinated Methyl, Phenylthio Homoallylic Alcohols [PDF]
Scientific Reports, 2017 Catalytic Asymmetric allylation of aldehydes with functionalized allylic reagents represents an important process in synthetic organic chemistry because the resulting chiral homoallylic alcohols are valuable building blocks in diverse research fields ...
Rui Guo +3 more
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A One-Pot Tandem Strategy in Catalytic Asymmetric Vinylogous Aldol Reaction of Homoallylic Alcohols [PDF]
Molecules, 2016 Reported is a rationally-designed one-pot sequential strategy that allows homoallylic alcohols to be employed in a catalytic, asymmetric, direct vinylogous aldol reaction with a series of activated acyclic ketones, including trifluoromethyl ketones, γ ...
Xufeng Hou +3 more
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A multicomponent approach for the preparation of homoallylic alcohols. [PDF]
Chem Sci, 2016 The generation of transient boronic acid species followed by their subsequent trapping with aldehydes as electrophiles to yield homoallylic alcohols, in a multicomponent and metal-free fashion.
Poh JS +5 more
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Selective bromochlorination of a homoallylic alcohol for the total synthesis of (−)-anverene [PDF]
Beilstein Journal of Organic Chemistry, 2016 The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the
Frederick J. Seidl, Noah Z. Burns
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Catalytic enantioselective epoxidation of tertiary allylic and homoallylic alcohols. [PDF]
J Am Chem Soc, 2013 An efficient and versatile method for the enantioselective epoxidation of both tertiary allylic and homoallylic alcohols catalyzed by Hf(IV)-bishydroxamic acid (BHA) complexes is described. Asymmetric epoxidation, kinetic resolution, and desymmetrization have been developed, demonstrating the flexible nature of the Hf(IV)-BHA system.
Olivares-Romero JL, Li Z, Yamamoto H.
europepmc +4 more sources
Olefin exchange-mediated cyclopropanation of nitriles with homoallylic alcohols [PDF]
Tetrahedron Letters, 2008 We report herein olefin exchange-mediated cyclopropanation of nitriles with homoallylic alcohols. The use of homoallylic alcohols is central to the successful implementation.
Jin Kun Cha
exaly +3 more sources
Amines tuned controllable carbonylation for the synthesis of γ-lactones and 1,4-diones [PDF]
Nature CommunicationsIn divergent carbonylative transformations using identical starting substrates, ligand-assisted transition metal catalysis has dominated selectively controllable transformations. However, achieving precise control of CO insertion in transition-metal-free
Yuanrui Wang +6 more
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