Iodine-Catalyzed Prins Cyclization of Homoallylic Alcohols and Aldehydes [PDF]
Molecules, 2013 The iodine-catalyzed Prins cyclization of homoallylic alcohols and aldehydes was investigated under metal-free conditions and without additives. Anhydrous conditions and inert atmosphere are not required.
Luiz F. Silva +4 more
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Chiral Syn-1,3-diol Derivatives via a One-Pot Diastereoselective Carboxylation/ Bromocyclization of Homoallylic Alcohols [PDF]
iScience, 2018 Summary: Chiral syn-1,3-diols are fundamental structural motifs in many natural products and drugs. The traditional Narasaka-Prasad diastereoselective reduction from chiral β-hydroxyketones is an important process for the synthesis of these ...
Guanxin Huang +7 more
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Barbier-type anti-Diastereo- and Enantioselective Synthesis of β-Trimethylsilyl, Fluorinated Methyl, Phenylthio Homoallylic Alcohols [PDF]
Scientific Reports, 2017 Catalytic Asymmetric allylation of aldehydes with functionalized allylic reagents represents an important process in synthetic organic chemistry because the resulting chiral homoallylic alcohols are valuable building blocks in diverse research fields ...
Rui Guo +3 more
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A One-Pot Tandem Strategy in Catalytic Asymmetric Vinylogous Aldol Reaction of Homoallylic Alcohols [PDF]
Molecules, 2016 Reported is a rationally-designed one-pot sequential strategy that allows homoallylic alcohols to be employed in a catalytic, asymmetric, direct vinylogous aldol reaction with a series of activated acyclic ketones, including trifluoromethyl ketones, γ ...
Xufeng Hou +3 more
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Keck asymmetric allylation in natural product synthesis: applications and developments (2018–2026) [PDF]
RSC AdvancesFollowing our 2017 comprehensive review, this update highlights the evolving and pivotal role of the Ti–BINOL-catalyzed Keck asymmetric allylation in modern total synthesis.
Kiran Zafar +5 more
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Catalytic Markovnikov hydrophosphorylation of unactivated olefins via a radical-polar crossover rearrangement [PDF]
Nature CommunicationsThe phosphorylation of alkenes offers a diverse handle for obtaining organophosphoryls, but its regioselectivity still faces challenges, especially the radical Markovnikov hydrophosphorylation of alkenes.
Yi-Fan Li, Hong-Chen Wang, Bing Han
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Amines tuned controllable carbonylation for the synthesis of γ-lactones and 1,4-diones [PDF]
Nature CommunicationsIn divergent carbonylative transformations using identical starting substrates, ligand-assisted transition metal catalysis has dominated selectively controllable transformations. However, achieving precise control of CO insertion in transition-metal-free
Yuanrui Wang +6 more
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Application of beta zeolite in allylation reaction aiming formation of new C-C bonds [PDF]
Cerâmica, 2020 This study describes the formation of new C-C bonds through the allylation reaction of different aldehydes promoted by beta zeolite. This environmentally friendly method was characterized by its efficiency, versatility, and chemoselectivity in the ...
V. K. S. A. Macedo +5 more
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Catalysis Communications, 2021 Asymmetric allylation and vinylation of aldehydes with allyl halides and vinyl halides have been achieved using the chromium(II)-oxazoline catalyst.
Sharad V. Kumbhar, Chinpiao Chen
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Molecules, 2002 Substituted homoallylic alcohols have been synthesised both by [2,3]-Wittig rearrangement of unsymmetrical bis-allylic ethers and reaction of alkenyl chloromethyl oxiranes with Mg/THF.
A. Acar, S. Servi
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