Results 31 to 40 of about 10,332 (223)
Novel Chiral Bis-Phosphoramides as Organocatalysts for Tetrachlorosilane-Mediated Reactions
The formation of novel chiral bidentate phosphoroamides structures able to promote Lewis base-catalyzed Lewis acid-mediated reactions was investigated.
Sergio Rossi +3 more
doaj +1 more source
Reactivity of Phenol Allylation Using Phase-Transfer Catalysis in Ion-Exchange Membrane Reactor
This study investigates the reactivity of phenol allylation using quaternary ammonium salt as a phase-transfer catalyst in three types of membrane reactors.
Ho Shing Wu, Yeng Shing Fu
doaj +1 more source
Palladium-catalyzed allylation of norbornadiene: Experimental and quantum chemical research
Objectives. Catalytic processes involving norbornadiene (NBD) and norbornene (NBN) derivatives provide exceptional opportunities for the synthesis of a wide range of carbocyclic hydrocarbons.
S. A. Durakov +3 more
doaj +1 more source
Rapid decarboxylative allylation of nitroalkanes [PDF]
Allyl nitroacetates undergo decarboxylative allylation to provide tertiary nitroalkanes in high yield. Moreover, the transformations are complete within several minutes under ambient conditions. High yields result because O-allylation of the intermediate
Tunge, Jon A. +3 more
core +1 more source
Pd-Catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allylstannanes [PDF]
A dearomative C4-allylation of benzyl ammoniums with allylstannanes by a palladium catalysis is described. A triarylphosphine-ligated palladium catalyst, which is capable of cleaving benzylic C–N bonds, realized facile dearomative reactions with C4 ...
Kei Muto (8586366) +7 more
core +1 more source
Platinum-Catalyzed Allylation of 2,3-Disubstituted Indoles with Allylic Acetates
Given the importance of heterocycle indole derivatives, much effort has been directed toward the development of methods for functionalization of the indole nucleus at N1 and C3 sites.
Bai-Jing Peng +2 more
doaj +1 more source
Copper-Catalyzed Enantioselective Allyl–Allyl Cross-Coupling [PDF]
A Cu(I)-phosphoramidite-based catalytic system that allows asymmetric allyl-allyl cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of functionalized substrates. The versatility of this new reaction is illustrated in the catalytic asymmetric synthesis of the Martinelline alkaloids chromene derivative
Hornillos, Valentin +3 more
openaire +2 more sources
Origin of Protonation Side Products in Pd-Catalyzed Decarboxylative Allylation Reactions: Evidence for In Situ Modification of Triphenylphosphine Ligand [PDF]
Palladium-catalyzed decarboxylative allylation (DcA) is a well-established method of carbon-carbon bond formation. This type of coupling is quite attractive, as the only byproduct is CO2.
Monica A., Gill +2 more
core +1 more source
The organo-catalyzed enantioselective benzylation reaction of α-trifluoromethoxy indanones afforded α-benzyl-α-trifluoromethoxy indanones with a tetrasubstituted stereogenic carbon center in excellent yield with moderate enantioselectivity
Yumeng Liang +3 more
doaj +1 more source
Unprecedented tandem allylic alkylation/intermolecular Michael addition was used in the preparation of novel bicyclic azalides. NMR spectroscopy was used not only to unambiguously determine and characterize the structures of these unexpected products of ...
Sulejman Alihodžić +3 more
doaj +1 more source

