Results 71 to 80 of about 12,893 (216)
Stereochemical Control in the Matteson Reaction
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley +1 more source
Selective N‐Functionalization of Pyrazoles
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek +2 more
wiley +1 more source
New Radical Allylation Reaction of Iodides
New Radical Allylation Reaction of ...
Frédéric Le Guyader (3001119) +3 more
core +1 more source
Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane
Easily accessible chiral phosphoric acid 1b has been applied as efficient organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilane.
Fan Tiantian +3 more
core
Diastereo- and Enantioselective Allylation of Substituted Nitroalkanes
Diastereo- and Enantioselective Allylation of Substituted ...
Barry M. Trost (1309395) +1 more
core +1 more source
Sustainable Diepoxide Monomers for Polyoxazolidinone‐Based High‐Performance Thermoplastics
Sustainable diglycidyl ethers could replace bisphenol A diglycidyl ether (BADGE) as a building block for polyoxazolidinones, yielding high‐performance thermoplastics with similar thermal and mechanical properties. Owing to their outstanding mechanical, thermal, and chemical properties, polyoxazolidinones, which are accessible from the reaction of ...
Lisa Van Emelen +14 more
wiley +1 more source
New Concept in the Allylation of Aldehydes: Regiospecific Allylation of Aldehydes by an Allyl-Transfer Reaction of Homoallylic ...
Hiroyuki Matsuura (3004563) +3 more
core +1 more source
An additive-free nickel-catalyzed alpha-allylation of aldehydes with allyl alcohol is reported. The reaction is promoted by 1 mol% of in situ formed nickel complex in methanol, and water is the sole by-product of the reaction. The experimental conditions
Mathieu Sauthier +7 more
core +1 more source
The development of a greener allylation reagent for α?allylation of carbonyl compounds is of great necessity. Here we present allyltrimethylsilane as a novel allylation reagent in the photoredox?catalyzed α?allylation of carbonyl compounds such as ...
곤탈라 아르준 슈크리칸트 +2 more
core +1 more source
Enzymatic Allylation of Catechols
Enzymatic allylation of catechols was realized via catechol O-methyltransferase (COMT) using an allylated S-adenosyl-L-methionine (allyl-SAM) analog, with relatively good chemo- and regioselectivities.
Liu, Yuxue +5 more
core +1 more source

