Results 71 to 80 of about 12,893 (216)

Stereochemical Control in the Matteson Reaction

open access: yesChemistry – A European Journal, Volume 32, Issue 40, 27 October 2026.
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley   +1 more source

Selective N‐Functionalization of Pyrazoles

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 40, 27 October 2026.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek   +2 more
wiley   +1 more source

New Radical Allylation Reaction of Iodides

open access: yes, 2016
New Radical Allylation Reaction of ...
Frédéric Le Guyader (3001119)   +3 more
core   +1 more source

Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane

open access: yes, 2011
Easily accessible chiral phosphoric acid 1b has been applied as efficient organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilane.
Fan Tiantian   +3 more
core  

Diastereo- and Enantioselective Allylation of Substituted Nitroalkanes

open access: yes, 2016
Diastereo- and Enantioselective Allylation of Substituted ...
Barry M. Trost (1309395)   +1 more
core   +1 more source

Sustainable Diepoxide Monomers for Polyoxazolidinone‐Based High‐Performance Thermoplastics

open access: yesChemSusChem, Volume 19, Issue 19, 14 October 2026.
Sustainable diglycidyl ethers could replace bisphenol A diglycidyl ether (BADGE) as a building block for polyoxazolidinones, yielding high‐performance thermoplastics with similar thermal and mechanical properties. Owing to their outstanding mechanical, thermal, and chemical properties, polyoxazolidinones, which are accessible from the reaction of ...
Lisa Van Emelen   +14 more
wiley   +1 more source

New Concept in the Allylation of Aldehydes:  Regiospecific Allylation of Aldehydes by an Allyl-Transfer Reaction of Homoallylic Alcohols

open access: yes, 2016
New Concept in the Allylation of Aldehydes:  Regiospecific Allylation of Aldehydes by an Allyl-Transfer Reaction of Homoallylic ...
Hiroyuki Matsuura (3004563)   +3 more
core   +1 more source

Nickel-catalyzed α-allylation of aldehydes and tandem aldol condensation/allylation reaction with allylic alcohols

open access: yes, 2017
An additive-free nickel-catalyzed alpha-allylation of aldehydes with allyl alcohol is reported. The reaction is promoted by 1 mol% of in situ formed nickel complex in methanol, and water is the sole by-product of the reaction. The experimental conditions
Mathieu Sauthier   +7 more
core   +1 more source

Visible-Light Photoredox-Catalyzed α-Allylation of α-Bromocarbonyl Compounds Using Allyltrimethylsilane

open access: yes, 2021
The development of a greener allylation reagent for α?allylation of carbonyl compounds is of great necessity. Here we present allyltrimethylsilane as a novel allylation reagent in the photoredox?catalyzed α?allylation of carbonyl compounds such as ...
곤탈라 아르준 슈크리칸트   +2 more
core   +1 more source

Enzymatic Allylation of Catechols

open access: yes, 2015
Enzymatic allylation of catechols was realized via catechol O-methyltransferase (COMT) using an allylated S-adenosyl-L-methionine (allyl-SAM) analog, with relatively good chemo- and regioselectivities.
Liu, Yuxue   +5 more
core   +1 more source

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