Results 91 to 100 of about 12,893 (216)

Catalytic Asymmetric Allylation of Aldehydes with Alkenes Mediated by Organophotoredox and Chiral Chromium Hybrid Catalysis [PDF]

open access: yes, 2018
A hybrid system accomplishing cooperativity between an organophotoredox acridinium catalyst and a chiral chromiumcomplex catalyst was developed, enabling the unprecedented exploitation of unactivated hydrocarbon alkenes as precursors to chiral ...
Kei, Ohkubo   +4 more
core   +1 more source

Iron-catalyzed allylation of ketones

open access: yes, 2006
Allylation of ketones has been efficiently performed using iron-complex catalysis and led to homoallylic alcohols in high ...
Durandetti, Muriel, Perichon, Jacques
core   +2 more sources

Enantioselective allylation of thiophene-2-carbaldehyde [PDF]

open access: yes, 2012
The first part of the bachelor thesis deals with enantioselective allylation of thiophene-2- carbaldehyde to the corresponding chiral homoallylic alcohol by using chiral Lewis bases as catalysts. The highest asymmetric induction achieved was 97 % ee. The
Motloch, Petr
core  

Inherent directing group enabled, Co(III)-catalyzed C-H allylation/ vi-nylation of isoquinolones [PDF]

open access: yes
The site-selective C8-allylation and vinylation of isoquinolones have been accomplished using allyl acetate and vinyl acetate and oxo group of isoquinolone as an inherent directing group in the presence of Co(III) catalysis. A plausible mechanism for the
Tamanna , Sharma   +3 more
core   +1 more source

Palladium−Indium Iodide-Mediated Allylation and Propargylation of Glyoxylic Oxime Ether and Hydrazone:  The Role of Water in Directing the Diastereoselective Allylation

open access: yes, 2016
Allylation and propargylation of glyoxylic oxime ether in the presence of a catalytic amount of palladium(0) complex and indium(I) iodide were studied.
Yousuke Yamaoka (1557157)   +3 more
core   +2 more sources

The tandem catalytic asymmetric allene diboration/imine allylation and the asymmetric transition-metal-catalyzed conjugate allylation of activated enones [PDF]

open access: yes, 2008
Thesis advisor: James P. MorkenDescribed herein are methods for asymmetric allylation. Chapter 1 describes the scope of the Pd-catalyzed asymmetric diboration of prochiral allenes.
Sieber, Joshua Daniel
core  

Electrochemical allylations in a deep eutectic solvent

open access: yesBeilstein Journal of Organic Chemistry
Electrosynthesis is a technique that is attracting increased attention and has many appealing features, particularly its potential greenness. At the same time, electrosynthesis requires a solvent and a supporting electrolyte in order for current to pass ...
Sophia Taylor, Scott T. Handy
doaj   +1 more source

SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT

open access: yesScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry, 2011
It has been established the possibility for phenol allylation on natural zeolites and them analogs. Here is demonstrated the synthesis of allyl phenol, which has wide industrial applications.
Gagik Torosyan, Dezy Hovhannisyan
doaj  

‐Allylation of α‐Hydroxy Carbonyl Compounds

open access: yes, 2006
alpha-Hydroxy carbonyl compounds undergo smooth O-allylation using allylic carbonates and Pd(0) catalysts. This method has significant advantages over other O-allylation methods as it provides a solution to several problems previously observed for this ...
Schmidt, Bernd (Prof. Dr.)   +3 more
core   +1 more source

Allyl Syringate

open access: yesMolbank
Syringic acid (1) is a naturally occurring compound with diverse biological activities. Structural modification of syringic acid often enhances its utility; however, the spectroscopic data for several derivatives remain unreported, and the procedures to ...
Naruedech Thimpa   +3 more
doaj   +1 more source

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