Results 101 to 110 of about 10,332 (223)

Bi-mediated allylation of aldehydes in [bmim][Br]: a mechanistic investigation

open access: yesBeilstein Journal of Organic Chemistry, 2018
The inexpensive room temperature ionic liquid (RTIL), [bmim][Br] has been found to be a superior medium for the Bi-mediated Barbier-type allylation of aldehydes compared to other conventional solvents.
Mrunesh Koli   +3 more
doaj   +1 more source

Indium-mediated allylation in carbohydrate synthesis: A short and efficient approach towards higher 2-acetamido-2-deoxy sugars

open access: yesBeilstein Journal of Organic Chemistry, 2014
Higher aminosugars are interesting targets in carbohydrate synthesis since these compounds play important roles in biological systems. However, their availability from natural sources is limited.
Christopher Albler   +3 more
doaj   +1 more source

Photochemical Asymmetric Palladium-Catalyzed Allylation Reaction: Expeditious Entry to Chiral 1,2-Amino Alcohols and 1,2-Diamines [PDF]

open access: yes
The construction of diverse alkylamines is of importance in drug discovery and natural product synthesis. Herein, we report an efficient photoredox/palladium dual catalysis for the construction of protected 1,2-amino alcohols and 1,2-diamines via ...
Haohua, Chen   +4 more
core   +1 more source

Synthesis of Chiral 1,3-Dienes through Ring-Closing Metathesis of Enantioenriched Enynes: Potential Precursors of Morphane Analogs

open access: yesAnais da Academia Brasileira de Ciências
A simple methodology for the synthesis of enynes by indium mediated diastereoselective allylation of aromatic N-tert-butanesulfinylimines bearing alkenyl groups at ortho-position with allyl bromide has been developed.
MARÍA JESÚS GARCIA-MUÑOZ   +3 more
doaj   +1 more source

Iron-catalyzed allylation of ketones [PDF]

open access: yes, 2006
Allylation of ketones has been efficiently performed using iron-complex catalysis and led to homoallylic alcohols in high ...
Durandetti, Muriel, Perichon, Jacques
core  

The tandem catalytic asymmetric allene diboration/imine allylation and the asymmetric transition-metal-catalyzed conjugate allylation of activated enones [PDF]

open access: yes, 2008
Thesis advisor: James P. MorkenDescribed herein are methods for asymmetric allylation. Chapter 1 describes the scope of the Pd-catalyzed asymmetric diboration of prochiral allenes.
Sieber, Joshua Daniel
core  

Electrochemical allylations in a deep eutectic solvent

open access: yesBeilstein Journal of Organic Chemistry
Electrosynthesis is a technique that is attracting increased attention and has many appealing features, particularly its potential greenness. At the same time, electrosynthesis requires a solvent and a supporting electrolyte in order for current to pass ...
Sophia Taylor, Scott T. Handy
doaj   +1 more source

SYNTHESIS OF ALLYL PHENYL ETHER AND CLAISEN REARRANGEMENT

open access: yesScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry, 2011
It has been established the possibility for phenol allylation on natural zeolites and them analogs. Here is demonstrated the synthesis of allyl phenol, which has wide industrial applications.
Gagik Torosyan, Dezy Hovhannisyan
doaj  

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