Results 101 to 110 of about 17,659 (225)
ElectrochemistryThe electrooxidative allylation of a carbamate was successfully demonstrated using 3-propylsulfonic acid-functionalized silica gel (Si-SCX-2). It was shown that the electrochemical oxidation of the carbamate as a first step yields the corresponding N ...
Haruka HOMMA +3 more
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MolbankSyringic acid (1) is a naturally occurring compound with diverse biological activities. Structural modification of syringic acid often enhances its utility; however, the spectroscopic data for several derivatives remain unreported, and the procedures to ...
Naruedech Thimpa +3 more
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Further exploration of the heterocyclic diversity accessible from the allylation chemistry of indigo
Beilstein Journal of Organic Chemistry, 2015 Diversity-directed synthesis based on the cascade allylation chemistry of indigo, with its embedded 2,2’-diindolic core, has resulted in rapid access to new examples of the hydroxy-8a,13-dihydroazepino[1,2-a:3,4-b']diindol-14(8H)-one skeleton in up to 51%
Alireza Shakoori +5 more
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Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation [PDF]
, 2008 General homogeneous conditions for the palladium-catalyzed synthesis of carbonyl compounds with tertiary carbon stereocenters at the α-position are reported.
Marinescu, Smaranda C. +3 more
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One-pot synthesis of 5-amino-2,5-dihydro-1-benzoxepines: access to pharmacologically active heterocyclic scaffolds [PDF]
, 2015 A one-pot multibond-forming process involving a thermally mediated Overman rearrangement and a ring closing metathesis reaction of allylic trichloroacetimidates bearing a 2-allyloxyaryl group has been developed for the synthesis of 5-amino-substituted 2 ...
Calder, Ewen D.D. +3 more
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Preparation of (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-) [PDF]
, 2009 [No ...
Krout, Michael R. +2 more
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Stereoselective synthesis of the published structure of synargentolide A and of one of its stereoisomers [PDF]
, 2005 A stereoselective synthesis is described of the structure published for the naturally occurring synargentolide A, an α,β-unsaturated lactone. The key steps of the synthesis were a Brown´s asymmetric allylation and a ring closing metathesis.
Carda, Miguel +3 more
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Bi-mediated allylation of aldehydes in [bmim][Br]: a mechanistic investigation
Beilstein Journal of Organic Chemistry, 2018 The inexpensive room temperature ionic liquid (RTIL), [bmim][Br] has been found to be a superior medium for the Bi-mediated Barbier-type allylation of aldehydes compared to other conventional solvents.
Mrunesh Koli +3 more
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Beilstein Journal of Organic Chemistry, 2014 Higher aminosugars are interesting targets in carbohydrate synthesis since these compounds play important roles in biological systems. However, their availability from natural sources is limited.
Christopher Albler +3 more
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Some aspects of radical chemistry in the assembly of complex molecular architectures
, 2013 International audienceThis review article describes briefly some of the radical processes developed in the authors' laboratory as they pertain to the concise assembly of complex molecular scaffolds.
Quiclet-Sire, Beatrice, Zard, Samir,
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