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Recent Advances Utilized in the Recycling of Homogeneous Catalysis.
The chemical record, 2019Homogeneous catalysts often show high activity and selectivity towards the various chemical transformations. Most of the transition metal-based active catalysts are expensive, rare, and have strict regulations for their use in pharmaceutical products ...
V. Shende, Vitthal B. Saptal, B. Bhanage
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2017
The performance of homogeneous catalysts is largely controlled by the ligands bound to the central metal. This chapter presents the most common concepts in Homogeneous Catalysis to rationalize and predict typical ligand influences. Those concepts and their particular predictive power are demonstrated based on selected examples.
Elisabeth Bouwman +2 more
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The performance of homogeneous catalysts is largely controlled by the ligands bound to the central metal. This chapter presents the most common concepts in Homogeneous Catalysis to rationalize and predict typical ligand influences. Those concepts and their particular predictive power are demonstrated based on selected examples.
Elisabeth Bouwman +2 more
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Microkinetic modeling in homogeneous catalysis
WIREs Computational Molecular Science, 2018Computational homogeneous catalysis has focused traditionally on the calculation of free energy barriers, which are ultimately related to rate constants.
M. Besora, F. Maseras
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2001
Catalysis by soluble complexes of transition metals is a rapidly gaining mode of catalysis in organic synthesis. These metals form bonds with one or more carbons in an organic reactant resulting in complexes that are known as organometallic complexes. Catalysis by these complexes is often referred to as homogeneous catalysis.
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Catalysis by soluble complexes of transition metals is a rapidly gaining mode of catalysis in organic synthesis. These metals form bonds with one or more carbons in an organic reactant resulting in complexes that are known as organometallic complexes. Catalysis by these complexes is often referred to as homogeneous catalysis.
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2016
This chapter explores homogeneous catalysis. A catalyst lowers the activation energy of a reaction, thereby accelerating it, by providing an alternative path that avoids the slow, rate-determining step of the uncatalysed reaction. A homogeneous catalyst is a catalyst in the same phase as the reaction mixture.
Peter Atkins +2 more
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This chapter explores homogeneous catalysis. A catalyst lowers the activation energy of a reaction, thereby accelerating it, by providing an alternative path that avoids the slow, rate-determining step of the uncatalysed reaction. A homogeneous catalyst is a catalyst in the same phase as the reaction mixture.
Peter Atkins +2 more
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General cross-coupling reactions with adaptive dynamic homogeneous catalysis
Nature, 2023I. Ghosh +7 more
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Improving Homogeneous Cationic Gold Catalysis through a Mechanism-Based Approach.
Accounts of Chemical Research, 2019Homogeneous gold catalysis is regarded as a landmark addition to the field of organic synthesis. It is the most effective way to activate alkynes for the addition of a diverse host of nucleophiles.
Zhichao Lu, G. Hammond, Bo Xu
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Chemical recycling of plastic wastes via homogeneous catalysis: A review
Chemical Engineering Journal, 2023Xueru Chen +4 more
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Homogeneous Catalysis: A Powerful Technology for the Modification of Important Biomolecules.
Chemistry - An Asian Journal, 2018Homogeneous catalysis plays an important and ubiquitous role in the synthesis of simple and complex molecules, including drug compounds, natural products, and agrochemicals.
Yogesh G Shelke +4 more
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Heterogenizing homogeneous catalysis
Advanced Materials, 1996A new method for heterogenizing homogeneous catalysts involving simple acid–base hydrolytic chemistry on inorganic oxide surfaces is described. It provides easy access to thin films containing terminal amine and phosphine donor ligands, which are precursors to a variety of oriented organometallic surfaces (see figure; L =CO, PR3). Opportunities for the
Maria G. L. Petrucci, Ashok K. Kakkar
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