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“HETEROGENIZING” HOMOGENEOUS CATALYSTS
Catalysis Reviews, 1974Abstract For many years, it has been customary to classify catalysts as “homogeneous” or “heterogeneous.” The former commonly operate through the formation of “intermediate compounds,” and the latter, by adsorption of the reactants on the catalyst surface.
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Homogenizing Metal Oxide Catalysts
Journal of Macromolecular Science: Part A - Chemistry, 1981Abstract Metal oxide particles have been prepared which are “soluble” in hydrocarbon solvents. The reaction of either a metal (or its metal oxide) with water, mineral spirits, and a mixture of carboxylic acids can result in hydrocarbon-miscible metal oxide core particles of 20-1000A diameter sizes which are coated with a layer of hydrophobic ...
Charles U. Pittman +2 more
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Are Heterogeneous Catalysts Precursors to Homogeneous Catalysts?
Journal of the American Chemical Society, 2001I W, Davies +3 more
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Polyoxometalates as Homogeneous Oxidation Catalysts
2012Anstract
CARRARO, MAURO +7 more
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Decomposition pathways of homogeneous catalysts
Applied Catalysis A: General, 2001Homogeneous catalysts can decompose in a variety of ways: metal deposition, ligand decomposition, reaction with impurities, dimer formation, and reaction of the metal center with the ligand. Sometimes these side reactions lead to temporary deactivation only and the catalyst activity can be restored. Without attempting to be complete, I have collected a
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Homogeneous and complex catalysts
Nature Synthesis, 2023Dongshuang Wu, Minna Cao
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Macromolecular ligands for homogeneous catalysts
Macromolecular Symposia, 1996AbstractStrategies to use macromolecular‐metal complexes in homogeneous catalysis are discussed and summarized. General advantages, problems and future opportunities in this broad research area are discussed.
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