Results 201 to 210 of about 993,004 (238)

Supramolecular Modulation of Photoinduced Charge Transfer: Tuning Between Tunneling and Incoherent Hopping

open access: yesAngewandte Chemie, EarlyView.
Molecular recognition guest binding can comprehensively modulate photoinduced charge‐transfer dynamics in the cyclophane host, including charge separation and recombination, via coherent superexchange and incoherent hopping. Unlike covalent donor–bridge–acceptor systems, this supramolecular approach avoids tedious syntheses and offers precise tuning of
Xueze Zhao   +11 more
wiley   +2 more sources

Cage‐Type Porous Organic Salts as Ship‐in‐a‐Bottle Nanoreactors for Light‐Transparent and Reusable Molecular Photocatalysts

open access: yesAngewandte Chemie, EarlyView.
Light‐transparent, cage‐type porous organic salts (POSs) function as nanoreactors that heterogenize molecularly defined photocatalysts through size exclusion. Photocatalysts are encapsulated intact during crystallization, providing confined yet accessible reaction fields under visible light without catalyst modification.
Kazuki Shiga   +5 more
wiley   +2 more sources

Tailoring Pt-Based Organometallic Porous Network on Ag(111): A Model System for "Host-Guest" Chemistry. [PDF]

open access: yesACS Nanosci Au
Carreño-Diaz V   +5 more
europepmc   +1 more source

Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement

open access: yesAngewandte Chemie, EarlyView.
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone   +8 more
wiley   +1 more source

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