Cyclo‐Polyproline: Chameleonic All‐Peptide Macrocycles With Induced‐Fit Host‐Guest Recognition
Macrocycles served as the genesis of supramolecular chemistry, advancing synthetic, separation, and materials fields. Despite their utility, they typically lack synthetic control. This work establishes a robust platform for all‐peptide macrocycles capable of host‐guest complexation and chameleonic behavior.
Camilla Di Girolamo +9 more
wiley +1 more source
Twisted Host-Guest Systems Exhibit Superamplification of Asymmetry via Coupled Strong Association and Helicity-Driven Cooperativity. [PDF]
Suzuki N +4 more
europepmc +1 more source
Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan +5 more
wiley +1 more source
"Impurity"-driven tunable organic room temperature phosphorescence <i>via</i> conformational regulation in multi host/guest systems. [PDF]
Dutta A, Singh U, Pati SK, Maitra U.
europepmc +1 more source
Glycine molecules induce a unique crystal packing into a supramolecular one‐dimensional columnar structure of octacyanidotungstates, which exhibits exceptionally strong antiferromagnetic superexchange interactions of J = −42.41(2) K between adjacent octacyanidotungstate units.
Tatsuya Konishi +8 more
wiley +1 more source
Molecular dynamics study of host-guest interactions between anticancer drugs and Cucurbit[8]uril nanocontainer. [PDF]
Ahmadian N +3 more
europepmc +1 more source
Supramolecular Lipid Nanoparticles Based on Amine β-CD Host-Guest Lipids: Design, Mechanisms, and Biosafety. [PDF]
Lv P +9 more
europepmc +1 more source
Real-time tracking of molecular cluster assembly and precise hierarchical reassembly into pure POM host-guest architecture. [PDF]
Zhu KL, Li K, Feng LB, Yang L, Chen JJ.
europepmc +1 more source
Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges
Controlling biological systems with small‐molecule chromophores has evolved into a powerful strategy and is applied from chemical biology to medicine. However, the complexity of in vivo systems cannot be matched by a single wavelength of light. Developing methods to combine and individually control multiple chromophores is crucial.
Nadja A. Simeth
wiley +1 more source
Supramolecularly gated enzymes: On-demand activity switching via host-guest competition for precision tumor therapy. [PDF]
Yang H +8 more
europepmc +1 more source

