Results 181 to 190 of about 253,481 (293)

Understanding the Role of Base in Catalytic Transfer Hydrogenation: A Comparative Review. [PDF]

Molecules
Taleb B, Al Mousawi A, Ghadban A, Hijazi I, Al Ahmar R, Bechelany M, Hijazi A.   +6 more
europepmc   +1 more source

A General Strategy for the Synthesis of Jerangolids Enabled by π‐allyl Stille Coupling

Chemistry – A European Journal, EarlyView.
A general strategy for the synthesis of jerangolids is established, featuring a late‐stage π‐allyl Stille coupling of two advanced, highly customizable building blocks to form the skipped diene core. The approach provides access to all naturally occurring jerangolids, including jerangolid H, whose configuration is confirmed by NMR analysis.
Janick Schug, Bernd Morgenstern, Johann Jauch   +2 more
wiley   +1 more source

Computational discovery of high-temperature superconducting ternary hydrides via deep learning. [PDF]

Natl Sci Rev
Wang X, Zhang C, Wang Z, Liu H, Lv J, Wang H, Weinan E, Ma Y.   +7 more
europepmc   +1 more source

Amine‐Triggered Azabenz‐Annulation of Cyclic Secondary Amine‐Functionalized Perylene Diimides for Dual‐Mode Sensing

Chemistry – A European Journal, EarlyView.
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park, Alejandro J. Cuellar de Lucio, Gregory C. Welch   +2 more
wiley   +1 more source

Enzymatic Metal-Hydrogen Atom Transfer with a Cobalt Protoporphyrin Cofactor. [PDF]

J Am Chem Soc
Masonheimer CL, Rourke MJ, Gardner RS, Hall RL, Perkins LJ, Brunold TC, Buller AR.   +6 more
europepmc   +1 more source

[Ti(py)4I2] as an Entry Point to Titanium(II) Chemistry via Titanium Metal Oxidation

Chemistry – A European Journal, EarlyView.
A strategically novel approach based on the oxidation of Ti metal enables access to Ti(II) chemistry. Controlled formation and complexation of Ti diiodide affords the Ti(II) complex [Ti(py)4I2], which serves as a convenient entry point to Ti(II) compounds.
Alexander Sedykh
wiley   +1 more source

Selective and Tunable Routes for Glucose to Fructose Conversion Using MgCl₂ Catalysis and Comparison to Other Metal Ions. [PDF]

ChemistryOpen
Maragani R, Meier S.
europepmc   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

Chemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis, Kyriakos D. Nikopoulos, Ioannis N. Lykakis   +2 more
wiley   +1 more source

Asymmetric Hydride Shift Reactions Catalyzed by Chiral Aluminium Complexes. [PDF]

Angew Chem Int Ed Engl
Amer MM, Hou J, Wang J, Mazeikaite A, Donohoe TJ.   +4 more
europepmc   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

Chemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin, Albane Fontaine, Jean‐Claude Berthet, Thibault Cantat   +3 more
wiley   +1 more source