Results 191 to 200 of about 253,481 (293)

Hydrosilylation of a Molecular Molybdenum Nitride Provides Mechanistic Insights into Photodriven Ammonia Synthesis from N₂ and H₂. [PDF]

J Am Chem Soc
Kim J, Kaul N, Pecoraro MV, Chirik PJ.
europepmc   +1 more source

An Electron‐Poor Nickel Diphosphine Complex: Synthesis, Structure, and Reactivity of Ni(dFppe)2

Chemistry – A European Journal, EarlyView.
Fluorinated diphosphine ligands such as 1,2‐bis[bis(pentafluorophenyl)phosphino]ethane (dFppe) offer powerful electronic tunability and unusual reactivity. Despite known analogues of the heavier congeners Pd and Pt, Ni complexes of dFppe remain conspicuously absent.
A. Dina Dilinaer, Marcus W. Drover
wiley   +1 more source

Cooperative metathesis of H-H/Sn-C^Ar bonds in stannylene-Ni⁰ systems. [PDF]

Chem Sci
Gilch JM, Keil PM, Iddrisu M, Szilvási T, Hadlington TJ.   +4 more
europepmc   +1 more source

Lewis‐Acidic Properties and Catalytic Behavior of Hydroboration‐ and Diolysis‐Derived NHC‐Stabilized Borenium Cations

Chemistry – A European Journal, EarlyView.
A series of thirteen (N‐heterocyclic carbene) NHC‐stabilized borenium cations is synthesized from NHC→BH3 complexes via hydroboration and condensation with diols. The novel compounds are fully characterized. Eight crystal structures are presented. Kinetic and NMR data show how the structural features translate to catalytic activity in hydrosilylation ...
Michał Jakubczyk, Michaela Buziková, Matouš Kloda, Miroslava Litecká, Karel Škoch   +4 more
wiley   +1 more source

Potassium-Doped Borophane Nanosheets: A Multifunctional Platform for Reversible Hydrogen Storage and Metal-Free Hydrogen Transfer. [PDF]

Small
Anju RS, Kumar P, Naikwadi DR, Baumgartner B, Chaudhary S, Bansode A, Konings MC, Ariese F, Batyrev ED, Gonugunta P, Srivastava VC, Murugavel R, Shiju NR.   +12 more
europepmc   +1 more source

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

Chemistry – A European Journal, EarlyView.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel, Shrouq Mujahed, Kamal Uddin Ansari, Katarzyna Młodzikowska‐Pieńko, Renana Gershoni‐Poranne, Yuri Tulchinsky   +5 more
wiley   +1 more source

Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives

Chemistry – A European Journal, EarlyView.
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch, Krzysztof Piech, Aurélien Crochet, Andreu Tortajada   +3 more
wiley   +1 more source

Cationic and Neutral Heterometallic Ir-Group 12 Element Polyhydride Compounds: Synthesis, Structure and Reactivity. [PDF]

Inorg Chem
Walsh AM, Martín-Fernández C, Lowe JP, Macgregor SA, Mahon MF, Whittlesey MK.   +5 more
europepmc   +1 more source

Hydride-Ion Conduction in Perovskite Hydride SrLiH3

Hydride-Ion Conduction in Perovskite Hydride SrLiH3
identifier:oai:t2r2.star.titech.ac.jp ...
openaire  

Self‐Complementary Dimers Based on Zwitterionic Halogen Bond Donors

Chemistry – A European Journal, EarlyView.
In this study we present the first isolated zwitterionic homodimers based on halogen bonding (XB). After optimization of the structures by changing the Lewis base (LB) and the backbone, their dimerization was observed in gas phase, as well as, in solid state.
Dana Kutzinski, Raffaella Papagna, Elric Engelage, Lianne H. E. Wieske, Mate Erdelyi, Stefan M. Huber   +5 more
wiley   +1 more source