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The article contains sections titled: 1. Introduction 2. Hydrides of the Alkali and Alkaline Earth Metals 2.1. General 2.2. Lithium Hydride 2.3. Sodium Hydride 2.4. Potassium Hydride 2.5. Beryllium Hydride 2.6. Magnesium Hydride 2.7. Calcium Hydride 3. Binary and Complex Hydrides of the Boron Group 3.1. General 3.2.
Wietelmann, U. +2 more
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Metal Hydride Vibrations: The Trans Effect of the Hydride
Inorganic Chemistry, 2019trans-Dihydride complexes are important in many homogeneous catalytic processes. Here vibrational spectroscopy and density functional theory (DFT) methods are used for the first time to reveal that 4d and 5d metals transmit more effectively than the 3d metals influence of the ligand trans to the hydride and also couple the motions of the trans-hydrides
David Schnieders +6 more
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The Journal of Physical Chemistry A, 2009
We have computed the structure and stability of the xenon hydrides HXeY (with Y = F, Cl, Br, I, CCH, CN, NC) using relativistic density functional theory (DFT) at ZORA-BP86/TZ2P level. All model systems HXeY studied here are bound equilibrium structures, but they are also significantly destabilized with respect to Xe and HY.
Perez-Peralta, N. +4 more
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We have computed the structure and stability of the xenon hydrides HXeY (with Y = F, Cl, Br, I, CCH, CN, NC) using relativistic density functional theory (DFT) at ZORA-BP86/TZ2P level. All model systems HXeY studied here are bound equilibrium structures, but they are also significantly destabilized with respect to Xe and HY.
Perez-Peralta, N. +4 more
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Hydriding and dehydriding kinetics of Dy2Co7 hydride
Journal of Alloys and Compounds, 1999The rates of hydrogen desorption from the β- and γ-phases of Dy2Co7 hydride, as well as hydrogen absorption into the α- and β-phases were measured and compared. This represents the first time that such comparisons have been made of two-phase transitions within the same intermetallic hydride.
L. Ming, A.J. Goudy
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2021
Hydrides are compounds in widespread use as reducing agents for the synthesis of metallic nanoparticles. Importantly, the formation of high yields of small noble metal nanoparticles with high crystallinity and monodisperse size distributions has been developed in part thanks to the use of such chemical species.
Miguel Comesaña-Hermo +2 more
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Hydrides are compounds in widespread use as reducing agents for the synthesis of metallic nanoparticles. Importantly, the formation of high yields of small noble metal nanoparticles with high crystallinity and monodisperse size distributions has been developed in part thanks to the use of such chemical species.
Miguel Comesaña-Hermo +2 more
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Light metal hydrides and complex hydrides for hydrogen storage
Chem. Commun., 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
Schüth, F. +2 more
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Formation of positronium hydride
Physical Review Letters, 1992We report the formation of positronium hydride (PsH), in collisions between positrons and methane. A preliminary value of 1.1\ifmmode\pm\else\textpm\fi{}0.2 eV for the binding energy of PsH is obtained.
Schrader, D. M. +3 more
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Rhodium Tetracarbonyl Hydride: The Elusive Metal Carbonyl Hydride
Angewandte Chemie International Edition, 200210.1002/1521-3773(20021018)41:203.0.CO;2-0 ; Angewandte Chemie - International Edition ; 41 ; 20 ; 3785-3789 ...
Li, C. +3 more
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Journal of Chemical & Engineering Data, 1961
BS>Solid-liquid equilibrium was investigated by the method of thermal analysis. The system LiH- Li2O was studied from 0 to 14 mole% Li2O and the system LiH- CaH2 from 0 to 37 mole % CaH2. The other two systems were investigated only at 8.0 plus or minus 0.3 mole% titanium hydride and zirconium hydride in LiH.
CHARLES E. MESSER +3 more
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BS>Solid-liquid equilibrium was investigated by the method of thermal analysis. The system LiH- Li2O was studied from 0 to 14 mole% Li2O and the system LiH- CaH2 from 0 to 37 mole % CaH2. The other two systems were investigated only at 8.0 plus or minus 0.3 mole% titanium hydride and zirconium hydride in LiH.
CHARLES E. MESSER +3 more
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