Atomic Tuning of Metal‐Support Interactions for Pathway‐Selective CO2 Photoreduction on TiO2
Single‐atom Fe and Cu catalysts anchored on TiO2 steer photocatalytic CO2 reduction toward distinct pathways. Fe sites favor rapid *CO desorption and selective CO formation, whereas Cu sites stabilize *CHO intermediates, enabling deep reduction and C─C coupling. Combined spectroscopy and DFT calculations reveal how metal–support interactions and oxygen
Dongyun Kim +13 more
wiley +1 more source
Topology‐Dependent Coke Formation in the Catalytic Pyrolysis of Phenol Over HFAU and HZSM‐5 Zeolites
The coke formation and speciation during the catalytic pyrolysis of lignin over different zeolite topologies were studied with a combination of operando EPR spectroscopy and ex situ pulsed techniques aided with DFT calculations. Operando EPR data showed that the coke formation in HFAU is fast compared to HZSM‐5.
Jörg W. A. Fischer +6 more
wiley +2 more sources
General method for prediction of thermal conductivity for well-characterized hydrocarbon mixtures and fuels up to extreme conditions using entropy scaling [PDF]
A general and efficient technique is developed to predict the thermal conductivity of well-characterized hydrocarbon mixtures, rocket propellant (RP) fuels, and jet fuels up to high temperatures and high pressures (HTHP).
Akhmedova-Azizova +72 more
core +1 more source
Tensile‐strained bismuth nanosheets (TS‐BiNs) achieve a formate Faradaic efficiency of 92% at −1000 mA cm−2 and enable stable production of pure formic acid (HCOOH) in a solid‐state electrolyte reactor. Theoretical calculations reveal that the introduced strain lowers the energy barrier for *OCHO intermediate formation, fundamentally enhancing the ...
Shiqi Li +16 more
wiley +1 more source
Room‐Temperature Gas‐Phase CO2‐to‐C3 Coupling by a 4f‐Aromatic Cluster
We engineered a 4f metalla aromatic cluster, PrB2C2−, that enables efficient sequential C−C coupling with CO2 at room temperature, yielding a linear C3 backbone. This system provides a complete theoretical catalytic cycle and establishes a new design principle for lanthanide mediated CO2 activation.
Feng‐Xiang Zhang +7 more
wiley +2 more sources
ANALYSIS OF HYDROCARBON TREATING SYSTEM TO THE EMISSION OFF SPARK-IGNITION FOUR-STROKE ENGINE
The reduction of carbon monoxide (CO), unburnthydrocarbon (UHC) emission and fuel consumption on spark-ignition four-stroke engine is continuously attempted. The purposes from this research were to determine the effect of Hydrocarbon Treating System (HTS)
Binyamin Binyamin +2 more
doaj
Fire-extinguishing efficiency and environmental performance of foam for extinguishing a warehouse space with oil [PDF]
This article analyzes the fire extinguishing efficiency of hydrocarbon and fluorinated film-forming foaming agent. It was revealed that fluorinated blowing agents have a number of significant advantages over hydrocarbon.
Degaev Evgeniy
doaj +1 more source
Studies of Thermochemical Heat Recovery of Exhaust Gases of Furnaces [PDF]
The review of schemes and methods of thermochemical heat recovery (TCR) of exhaust flue gas for different power plants operating on hydrocarbon fuels have been performed.
Gubinskiy, M.V. +2 more
core
A stimuli‐responsive supramolecular system has been rationally designed enabling hierarchical control over supramolecular handedness. This hybrid architecture retains orthogonal host‐guest properties and displays unique amphiphilicity‐directed chiral self‐assembly.
Minzan Zuo +8 more
wiley +1 more source
Fire extinguishing efficiency of hydrocarbon and fluorinated film-forming foaming agent [PDF]
This article analyzes the fire extinguishing efficiency of hydrocarbon and fluorinated film-forming foaming agent. It was revealed that fluorinated blowing agents have a number of significant advantages over hydrocarbon.
Vlasov Nikolay, Melnikov Artem
doaj +1 more source

