Results 101 to 110 of about 10,150 (215)

Synthesis, Solubilization, and Photophysical Properties of Polyfluorinated Pentacene Dimers

open access: yesJournal of Physical Organic Chemistry, Volume 39, Issue 7, July 2026.
The synthesis and photophysical analysis of polyfunctionalized pentacene dimers is described. Polyfluorination is employed to modulate the polarizability and to investigate the effects on the mechanism of singlet fission (SF). ABSTRACT A polyfluorinated pentacene dimer, linked with a 1,3‐diethynylphenylene spacer, was synthesized to investigate the ...
Zachary W. Schroeder   +10 more
wiley   +1 more source

Remarkable Formation of Indene Derivatives Upon Friedel–Crafts Acylation Reactions

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
This shows indene derivatives. Under the reaction conditions of a Friedel–Crafts acylation, alkyl benzenes underwent an unprecedented cyclopentannulation furnishing indene derivatives. Alkylbenzene derivatives react with two equivalents of pivaloyl chloride (PivCl) in the presence of aluminum trichloride under formation of indene derivatives with up to
Leah Bantel   +3 more
wiley   +1 more source

Anaerobic Degradation of Chlorinated Hydrocarbons in Groundwater Aquifers or "Chlorinated Hydrocarbon Degradation"

open access: yes, 1997
Groundwater contamination by chlorinated hydrocarbons, such as tetrachloroethene (PCE) or trichloroethene (TCE), is a major concern throughout the United States. A developing strategy for the remediation of PCE and TCE contaminated aquifers is anaerobic biodegradation.
Nielsen, R. Brent, Keasling, Jay D
openaire   +1 more source

Expanding the Toolbox for Biocatalytic Halogenation by Identification and Characterization of Three Vanadium Chloroperoxidases

open access: yesChemBioChem, Volume 27, Issue 11, 15 June 2026.
Schematic illustration of the workflow from DNA sequence‐based research to expression in shaking flasks and subsequent purification via IMAC. The obtained enzymes broaden the toolbox of enzymes used for halogenation reactions with differing catalytic properties and tolerances to reaction‐related conditions.
Sonja Schönrock   +2 more
wiley   +1 more source

MnCl2‐Catalyzed Photochemical Functionalization of Unactivated C(sp3)H Bonds

open access: yesChemSusChem, Volume 19, Issue 11, 15 June 2026.
A photochemical method enables the activation of alkanes, utilizing cheap and abundant MnCl2 as the photocatalyst. Alkenylation and alkylation reactions are performed, affording the desired products in good yields. Activation of inert C(sp3)H bonds is of great importance in organic synthesis, since it can functionalize unreactive molecules, such as ...
Naya A. Stini   +3 more
wiley   +1 more source

Processability and Crosslink Density: Role of Peptizers in Natural Rubber and Chlorobutyl Rubber

open access: yesJournal of Applied Polymer Science, Volume 143, Issue 22, June 10, 2026.
This work evaluates how chemical and physical peptizers affect mastication, vulcanization behavior, and network formation in natural rubber and chlorobutyl rubber. Size‐exclusion chromatography, rheometry, DSC, and swelling analyses demonstrate improved processability but reduced crosslink density with peptizer addition.
Amanda F. Baruel   +4 more
wiley   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 21, 4 June 2026.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar   +3 more
wiley   +1 more source

Occupational exposure to chlorinated solvents and lung cancer: results of the SYNERGY case-control study. [PDF]

open access: yesOccup Environ Med
Wan W   +41 more
europepmc   +1 more source

PVC Waste to Fuel: Pyrolysis Oil Upgrading through Catalytic Hydrodechlorination. [PDF]

open access: yesEnergy Fuels
Mahmoudi E   +6 more
europepmc   +1 more source

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