Results 101 to 110 of about 10,150 (215)
Synthesis, Solubilization, and Photophysical Properties of Polyfluorinated Pentacene Dimers
The synthesis and photophysical analysis of polyfunctionalized pentacene dimers is described. Polyfluorination is employed to modulate the polarizability and to investigate the effects on the mechanism of singlet fission (SF). ABSTRACT A polyfluorinated pentacene dimer, linked with a 1,3‐diethynylphenylene spacer, was synthesized to investigate the ...
Zachary W. Schroeder +10 more
wiley +1 more source
Remarkable Formation of Indene Derivatives Upon Friedel–Crafts Acylation Reactions
This shows indene derivatives. Under the reaction conditions of a Friedel–Crafts acylation, alkyl benzenes underwent an unprecedented cyclopentannulation furnishing indene derivatives. Alkylbenzene derivatives react with two equivalents of pivaloyl chloride (PivCl) in the presence of aluminum trichloride under formation of indene derivatives with up to
Leah Bantel +3 more
wiley +1 more source
Groundwater contamination by chlorinated hydrocarbons, such as tetrachloroethene (PCE) or trichloroethene (TCE), is a major concern throughout the United States. A developing strategy for the remediation of PCE and TCE contaminated aquifers is anaerobic biodegradation.
Nielsen, R. Brent, Keasling, Jay D
openaire +1 more source
Schematic illustration of the workflow from DNA sequence‐based research to expression in shaking flasks and subsequent purification via IMAC. The obtained enzymes broaden the toolbox of enzymes used for halogenation reactions with differing catalytic properties and tolerances to reaction‐related conditions.
Sonja Schönrock +2 more
wiley +1 more source
MnCl2‐Catalyzed Photochemical Functionalization of Unactivated C(sp3)H Bonds
A photochemical method enables the activation of alkanes, utilizing cheap and abundant MnCl2 as the photocatalyst. Alkenylation and alkylation reactions are performed, affording the desired products in good yields. Activation of inert C(sp3)H bonds is of great importance in organic synthesis, since it can functionalize unreactive molecules, such as ...
Naya A. Stini +3 more
wiley +1 more source
Processability and Crosslink Density: Role of Peptizers in Natural Rubber and Chlorobutyl Rubber
This work evaluates how chemical and physical peptizers affect mastication, vulcanization behavior, and network formation in natural rubber and chlorobutyl rubber. Size‐exclusion chromatography, rheometry, DSC, and swelling analyses demonstrate improved processability but reduced crosslink density with peptizer addition.
Amanda F. Baruel +4 more
wiley +1 more source
Solubilizing Nonpolar Substances in Polar Solvents: Strategies, Molecular Mechanisms, and Applications. [PDF]
Mu X, Wang R, Wang S, Wang X, Zhang Y.
europepmc +1 more source
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
Occupational exposure to chlorinated solvents and lung cancer: results of the SYNERGY case-control study. [PDF]
Wan W +41 more
europepmc +1 more source
PVC Waste to Fuel: Pyrolysis Oil Upgrading through Catalytic Hydrodechlorination. [PDF]
Mahmoudi E +6 more
europepmc +1 more source

