Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n‐Pentene
Angewandte Chemie, EarlyView.Alkene cracking in medium‐pore zeolites is governed by a balance of enthalpic and entropic effects. Intrinsic barriers are quantified and shown to be lower than for alkanes due to stabilization of carbenium‐ion‐like transition states. Confinement and extra‐framework aluminum modulate reactivity by tuning transition‐state energetics, providing a ...
Ruixue Zhao +4 more
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Solvent- and metal-free upcycling of low-density polyethylene using a practical ZSM-5/Al<sub>2</sub>O<sub>3</sub> bead catalyst. [PDF]
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Thermal cracking for upgrading medium-low maturity shale oil: evolution of organic matter occurrence. [PDF]
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Articles of Significant Interest in This Issue. [PDF]
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Determination of the Weight Percent of Aromatic Compounds in a Heavy Fuel Oil by Using Flash Chromatography and Solid-phase Extraction Coupled With High-Temperature Two-Dimensional Gas Chromatography and Electron Ionization Time-of-Flight High-Resolution Mass Spectrometry. [PDF]
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TOXICITY AND METABOLISM OF ALKYL-POLYCYCLIC AROMATIC HYDROCARBONS IN FISH
, 2008 Dominique Turcotte
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Measurement of stable carbon isotope ratios of non-methane hydrocarbons and halocarbons
, 2012 A. Zuiderweg
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