Results 101 to 110 of about 837,919 (319)

Efficient and Scalable Radiative Cooling for Photovoltaics Using Solution‐Processable and Solar‐Transparent Mesoporous Nanoparticles

open access: yesAdvanced Functional Materials, EarlyView.
Graded refractive index (GRI) structures are prepared from the layer‐by‐layer spray coating of the mesoporous SiO2 nanoparticles, showing high solar transparency and thermal emissivity. Under outdoor conditions, after 50 days, the GRI‐coated photovoltaics show on average 6.65 ± 1.48 °C lower than that of the non‐coated references, maintaining 80.9 ± 8 ...
Heesuk Jung   +14 more
wiley   +1 more source

2-Methyl-N-[(3-methyl-2-pyridyl)carbamothioyl]benzamide

open access: yesActa Crystallographica Section E, 2008
In the title compound, C15H15N3OS, the thiourea group is stabilized by an intramolecular hydrogen bond between the carbonyl O atom and the thioamide group. A C—H...N intramolecular hydrogen bond is also present.
R. H. Jusoh   +3 more
doaj   +1 more source

Mechanically Adaptable High‐Performance p(SBMA‐MMA) Copolymer Hydrogel with Iron (II/III) Perchlorate for Wearable Thermocell Applications

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
A high‐performance n‐type element for quasi‐solid‐state thermocells has been introduced, outperforming conventional p‐type elements and showcasing the potential to harness body heat as an energy source or power embedded sensors. This advance significantly contributes to waste thermal energy harvesting and wearable technology, paving the way for self ...
Gilyong Shin   +10 more
wiley   +1 more source

Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(4-nitrophenyl)methyl]amino}-3-phenylpropanoate

open access: yesActa Crystallographica Section E, 2012
The molecule of the title compound, C27H24N4O5, exists in the keto–enamine tautomeric form, stabilized by an intramolecular N—H...O hydrogen bond. An intramolecular C—H...·O hydrogen bond also occurs. In the crystal,
Xin Zhang   +3 more
doaj   +1 more source

Poly(1,4‐anthraquinone) as an Organic Electrode Material: Interplay of the Electronic and Structural Properties due to the Unusual Lone‐Pair‐π Conjugation

open access: yesAdvanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
In this study, the unique role of the unusual lone‐pair‐π conjugation mechanism in poly(1,4‐anthraquinone) (P14AQ) is explored as an organic electrode material. Unlike traditional π‐π interactions, P14AQ's conjugation involves lone pairs of oxygen atoms interacting with the π cloud of adjacent units, enabling stable charge transport even with minimal π‐
Xiaotong Zhang, Piotr de Silva
wiley   +1 more source

1-(4-Acetylphenyl)-3-butyrylthiourea

open access: yesActa Crystallographica Section E, 2008
The title compound, C13H16N2O2S, crystallizes in the thioamide form with an intramolecular hydrogen bond of type N—H...Obutyryl. Molecules are linked into chains parallel to [10overline{1}] by a further hydrogen bond of type N—H...Oacetyl. C&#
Moazzam Hussain Bhatti   +3 more
doaj   +1 more source

The Additivity of the Energies of Normal Covalent Bonds [PDF]

open access: yes, 1932
The chemical bond between two identical atoms, as in the molecules H2, Cl2, etc., may be considered as an example of a normal covalent bond, involving an electron pair shared by the two atoms.
Pauling, Linus, Yost, Don M.
core  

Circular hydrogen bonds [PDF]

open access: yesNature, 1979
CIRCULAR hydrogen bonds present a new, experimentally demonstrated principle showing how hydration water molecules and hydroxyl groups of macromolecules can cooperate to form a network-like pattern. Quantum chemical calculations show that chain-like H-bonds in the crystal lattice1 are energetically favoured above individual ones2,3.
openaire   +3 more sources

Exploring Dipolar Dynamics and Ionic Transport in Metal‐Organic Frameworks: Experimental and Theoretical Insights

open access: yesAdvanced Functional Materials, EarlyView.
In this study, the interplay of dipolar dynamics and ionic charge transport in MOF compounds is investigated. Synthesizing the novel structure CFA‐25 with integrated freely rotating dipolar groups, local and macroscopic effects, including interactions with Cs cations are explored.
Ralph Freund   +6 more
wiley   +1 more source

Effect of Intramolecular Hydrogen Bond Formation on the Abraham Model Solute Descriptors for Oxybenzone

open access: yesLiquids
Solute descriptors derived from experimental solubility data for oxybenzone dissolved in 21 different organic solvents indicate that the hydrogen atom on the hydroxyl functional group forms an intramolecular hydrogen bond with the lone electron pair on ...
Jocelyn Chen   +3 more
doaj   +1 more source

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