Results 151 to 160 of about 33,129 (257)

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

How does pharmacological and toxicological knowledge evolve? A case study on hydrogen cyanide in German pharmacology and toxicology textbooks from 1878 to 2020. [PDF]

Naunyn Schmiedebergs Arch Pharmacol
Ludwig L, Seifert R.
europepmc   +1 more source

Cyanogenesis in Macadamia and Direct Analysis of Hydrogen Cyanide in Macadamia Flowers, Leaves, Husks, and Nuts Using Selected Ion Flow Tube-Mass Spectrometry. [PDF]

Foods, 2020
Castada HZ, Liu J, Ann Barringer S, Huang X.   +3 more
europepmc   +1 more source

Ultra‐Fast and Economical Pre‐Breakdown Electrochemical Synthesis of Intrinsically Conductive Polymer Suspension for Production of Safe Lithium‐Ion Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This paper presents a breakthrough pre‐breakdown electrochemical method for synthesizing polyNiMeOSalen suspensions, achieving an 83% yield and nanoscale dispersion ($1500/kg) and environmental impact (1.42 kg CO2eq/kg). We report a novel pre‐breakdown electrochemical synthesis method for producing polyNiMeOSalen suspensions with exceptional ...
Evgenii Beletskii, Valentin Romanovski, Mikhail Pinchuk, Vadim Snetov, Alexey Volkov, Peixia Yang, Yurii K. Gun'ko   +6 more
wiley   +1 more source

Membrane Engineering for Battery Systems: Bridging Design Principles and Frontier Applications

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The review emphasizes membrane separators' role in battery performance and safety, covering redox flow, lithium‐ion, and solid‐state batteries. It reviews advances in membrane materials (e.g., polymer electrolytes, hybrid composites) and ion transport mechanisms, while addressing challenges like dendrite growth and crossover losses.
Xiaoqun Zhou, Justice Delali Akoto, Rui Tan, Jun Ma   +3 more
wiley   +1 more source

Interfacial Solvent Molecular Engineering via High‐Safety Dense Separators for High‐Rate Lithium‐Ion Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The dense PPS‐separator prevents thermal runaway by allowing electron transfer through the steel needle during penetration, while the residual electrolyte enables brief ion migration and Joule heating, causing rapid electrolyte vaporization, collapse of the ion transport network, and a sharp drop in ionic conductivity.
Haitao Zhou, Jie Gu, Haiyun Zhou, Yihong Deng, Yafei Shi, Yang Yang, Chen Wang, Hongquan Gao, Jianchun Wu, Libo Wang, Xiangdong Huo   +10 more
wiley   +1 more source

Myocardial inflammation is associated with impaired mitochondrial oxidative capacity in ischaemic cardiomyopathy

ESC Heart Failure, Volume 12, Issue 2, Page 1246-1255, April 2025.
Abstract Aims Myocardial inflammation and impaired mitochondrial oxidative capacity are hallmarks of heart failure (HF) pathophysiology. The extent of myocardial inflammation in patients suffering from ischaemic cardiomyopathy (ICM) or dilated cardiomyopathy (DCM) and its association with mitochondrial energy metabolism are unknown.
Julius Borger, Elric Zweck, Constanze Moos, Patrick Horn, Fabian Voß, Heinz‐Peter Schultheiss, Jacob Eifer Møller, Udo Boeken, Hug Aubin, Artur Lichtenberg, Malte Kelm, Michael Roden, Amin Polzin, Ralf Westenfeld, Julia Szendroedi, Daniel Scheiber   +15 more
wiley   +1 more source

Rigid Ligand Environments at Beryllium, From Spectroscopic Probes to Small Molecule Activation

European Journal of Inorganic Chemistry, EarlyView.
Due to the high rigidity and definition of beryllium scorpionate complexes, they can be used to study metal‐pseudohalide and ‐carbon bonds in detail. Furthermore, these compounds can be used to activate small molecules and exhibit unprecedented transmetalation reactions. In beryllium scorpionate complexes, three of the four available coordination sites
Magnus R. Buchner, Chantsalmaa Berthold
wiley   +1 more source

Triptindane‐9,10,11‐triol: Threefold Hydride Transfer from Lithium Aluminum Hydride as the Key Step to C3‐Symmetrically Trifunctionalized Tribenzo[3.3.3]propellanes

European Journal of Organic Chemistry, EarlyView.
Threefold reduction of 9,10,11‐triptindanetrione with LiAlH4 or NaBH4 yields exclusively the C3‐symmetric triol, suggesting an intracomplex (“rolling”) mechanism. However, use of LiAlH4/LiAlD4 (1 : 1) reveals a preceding hydride exchange. Mechanistic implications are discussed including the reduction of the related diketone.
Thorsten Hackfort, Bernhard M. Malorny, Andreas Mix, Beate Neumann, Hans‐Georg Stammler, Dietmar Kuck   +5 more
wiley   +1 more source

Biological hydrogen cyanide emission globally impacts the physiology of both HCN-emitting and HCN-perceivingPseudomonas

, 2021
Anand A, Falquet L, Abou-Mansour E, L’Haridon F, Keel C, Weisskopf L.   +5 more
europepmc   +1 more source