Results 171 to 180 of about 87,044 (337)

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

ChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank, Ádám Horváth, Duy Nguyen, Moritz J. Ernst, Simon Steinhauer, Zoltán Benkő, Christian Müller   +6 more
wiley   +1 more source

Fast Sensing of Hydrogen Cyanide (HCN) Vapors Using a Hand-Held Ion Mobility Spectrometer with Nonradioactive Ionization Source. [PDF]

Sensors (Basel), 2021
Bocos-Bintintan V, Ratiu IA.
europepmc   +1 more source

Skeletal Editing from Pyridine to Aniline via C‐Insertion and N‐Isomerization

ChemistryEurope, EarlyView.
A concise protocol is presented that converts pyridines into anilines by externalizing the original pyridine nitrogen at either the "ipso" or "ortho" position, which results in para or meta‐primary aniline products. A key carbene‐insertion step precedes nitrogen migration, preserving both ring size and overall structure.
Yun Luo, Jing Dai, Yongchang Wei, Chang Min   +3 more
wiley   +1 more source

Transcriptome and Coexpression Network Analyses Provide In-Sights into the Molecular Mechanisms of Hydrogen Cyanide Synthesis during Seed Development in Common Vetch (Vicia sativa L.). [PDF]

Int J Mol Sci, 2022
Li M, Zhao L, Zhou Q, Fang L, Luo D, Liu W, Searle IR, Liu Z.   +7 more
europepmc   +1 more source

Advances in Triboelectric Nanogenerators With Rotating Structure

Carbon Energy, EarlyView.
The rotating TENG has been widely studied for its superiorities of simple structure, high efficiency, and stable output. This review introduced the four different principles of rotating TENG and offered a thorough summary for performance and application research through three‐level classification. Importantly, the current existing problems, challenges,
Chuguo Zhang, Chunxu Xue, Yutong Chen, Yujie Qiang, Seeram Ramakrishna   +4 more
wiley   +1 more source

A Review on Applications and Challenges of Fullerenes in Proton Exchange Membranes

Carbon Energy, EarlyView.
This review is devoted to the analysis of the use of fullerenes and their functionalized derivatives to improve the efficiency of proton exchange membranes. The synthetic methods, structure, properties, and proton transfer mechanisms of fullerene‐containing membranes are discussed in detail. Promising areas of scientific research are discussed, and key
Ruslan Usmanov, Alexander Pozdnyakov
wiley   +1 more source

Regulating Interfacial Hydrogen‐Bonding Connectivity by Oxygen Vacancies‐Driven [Fe(CN)6]3− Coordination for Boosting Hydrogen Peroxide Electrosynthesis

Carbon Energy, EarlyView.
ABSTRACT The inherent hydroxide‐rich (OH⁻) environment in alkaline media facilitates the two‐electron oxygen reduction reaction (2e−ORR). However, the strong interaction between alkali metal cations and solvated water molecules significantly reduces the connectivity of the hydrogen bond network within the alkaline electric double layer, thereby ...
Kaiming Li, Ben Huang, Aihao Xu, Kai Nie, Xianhai Bai, Qian Ning, Guodong Wang, Shiming Qiu, Huibing He, Yang Ren, Jing Xu, Xucai Yin   +11 more
wiley   +1 more source

The ventilation of houses after fumigation with hydrogen cyanide [PDF]

, 1939
A. B. P. Page, O. F. Lubatti, F. P. Gloyns   +2 more
openalex   +1 more source

Hydrogen cyanide acts as a regulator of reactive oxygen species metabolism. [PDF]

Planta
Piekarniak M, Weston LA, Gniazdowska A, Krasuska U.   +3 more
europepmc   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source