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Hydrogen exchange in ?-cyclopentadienyl-?-(3)-1,2-dicarbollylcobalt and the CH-acidity of the cyclopentadienyl and dicarbollyl ligands

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1978
1. Study of isotopic hydrogen exchange in π-cyclopentadienyl-π-dicarbollylcobalt in basic solution has shown that the hydrogen of the C-H bond of the dicarbollyl ligand enters into reaction 100 times more rapidly than the hydrogen of the cyclopentadienyl ligand. 2.
E. V. Bykova   +5 more
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Extraction distribution of microamounts of cesium in the two-phase water-HCl-nitrobenzene-benzo-18-crown-6-hydrogen dicarbollylcobaltate system

Journal of Radioanalytical and Nuclear Chemistry, 2005
Extraction of microamounts of cesium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of benzo-18-crown-6 (B18C6,L) has been investigated. The equilibrium data have been explained assuming that the HL+, CsL+ and CsL complexes are extracted into the organic phase.
Z. Valentová, P. Vaňura, E. Makrlík
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Solvent extraction of cesium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and polypropylene glycol PPG 425

Journal of Radioanalytical and Nuclear Chemistry, 2010
Extraction of microamounts of cesium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of polypropylene glycol PPG 425 (L) has been investigated. The equilibrium data have been explained assuming that the complex species HL+ and CsL+ (L = PPG 425) are extracted into the organic phase.
E. Makrlík, P. Vaňura, P. Selucký
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Extraction of Microamounts of Calcium and Strontium into Nitrobenzene by Using Hydrogen Dicarbollylcobaltate in the Presence of “Classical” CMPO

Zeitschrift für Physikalische Chemie, 2009
Abstract Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of octyl-phenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (“classical” CMPO, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+, HL2
E. Makrlík, P. Vanura, P. Selucky
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Extraction of microamounts of strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dicyclohexyl-18-crown-6

Journal of Radioanalytical and Nuclear Chemistry, 2006
Extraction of microamounts of strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of dicyclohexyl-18-crown-6 (DCH18C6, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+, HL, SrL2+and SrL are extracted into the organic phase.
Z. Valentová, P. Vaňura, E. Makrlík
openaire   +1 more source

Extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and tetraisopropyl methylene diphosphonate

Journal of Radioanalytical and Nuclear Chemistry, 2010
Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of tetraisopropyl methylene diphosphonate [T(iPr)MDP, L] has been investigated. The equilibrium data have been explained assuming that the complexes HL+, HL2+, ML23+, ML33+ and ML43+ (M3+ = Eu3+, Am3+) are extracted ...
E. Makrlík, P. Vaňura, P. Selucký
openaire   +1 more source

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