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Journal of the American Chemical Society, 2007
A combined kinetic and DFT study of the uncatalyzed isomerization of cationic solvent complexes of the type cis-[Pt(R‘)(S)(PR3)2]+ (R‘ = linear and branched alkyls or aryls and S = solvents) to their trans isomers has shown that the reaction goes through the rate-determining dissociative loss of the weakly bonded molecule of the solvent and the ...
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A combined kinetic and DFT study of the uncatalyzed isomerization of cationic solvent complexes of the type cis-[Pt(R‘)(S)(PR3)2]+ (R‘ = linear and branched alkyls or aryls and S = solvents) to their trans isomers has shown that the reaction goes through the rate-determining dissociative loss of the weakly bonded molecule of the solvent and the ...
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Effect of Alkaloids on Hydrogen Overpotential
Nature, 1947IT is well known that certain substances, such as arsenious oxide1, when added to a solution in which is a working electrode evolving hydrogen, considerably increase the hydrogen overpotential at the cathode. Such substances are often referred to as 'poisons' 2, and a detailed knowledge of their effects on irreversible electrode potentials appears to ...
J O, BOCKRIS, B E, CONWAY
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Effect of Hydrogen on Surface of Niobium
MRS Proceedings, 1998ABSTRACTNiobium single crystals are used as substrate material for constructing superconducting quantum interference device or SQUID. The use of niobium is prompted by the fact that it is a low Tc metallic superconductor. In order to fabricate the device the surface of the crystal has to be polished flat.
Gadgil, V.J., Keim, E.G.
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