Results 11 to 20 of about 43,291 (164)

Reproducible measurements of the δ2H composition of non-exchangeable hydrogen in complex organic materials using the UniPrep2 online static vapour equilibration and sample drying system

open access: yesMethodsX, 2023
Non-exchangeable hydrogen-isotope (δ2Hn) measurements of complex organic samples are used in forensics to determine sample authenticity, traceability, and provenance.
Leonard I. Wassenaar   +3 more
doaj   +1 more source

Recent Progresses in Stable Isotope Analysis of Cellulose Extracted from Tree Rings

open access: yesPlants, 2021
In this work, the challenges and progression in stable isotope investigation, from the analytical tools and technical sample preparation procedures to the dendroclimatological experiments, were reviewed in terms of their use to assess tree physiological ...
Silviu-Laurentiu Badea   +2 more
doaj   +1 more source

Effects of alkalinity and salinity at low and high light intensity on hydrogen isotope fractionation of long-chain alkenones produced by Emiliania huxleyi [PDF]

open access: yesBiogeosciences, 2017
Over the last decade, hydrogen isotopes of long-chain alkenones have been shown to be a promising proxy for reconstructing paleo sea surface salinity due to a strong hydrogen isotope fractionation response to salinity across different environmental ...
G. M. Weiss   +6 more
doaj   +1 more source

Isotope Effects on Chemical Shifts in the Study of Hydrogen Bonds in Small Molecules

open access: yesMolecules, 2022
This review is giving a short introduction to the techniques used to investigate isotope effects on NMR chemical shifts. The review is discussing how isotope effects on chemical shifts can be used to elucidate the importance of either intra- or ...
Poul Erik Hansen
doaj   +1 more source

H2 Kinetic Isotope Fractionation Superimposed by Equilibrium Isotope Fractionation During Hydrogenase Activity of D. vulgaris Strain Miyazaki

open access: yesFrontiers in Microbiology, 2019
We determined 2H stable isotope fractionation at natural abundances associated with hydrogenase activity by whole cells of Desulfovibrio vulgaris strain Miyazaki F expressing a NiFe(Se) hydrogenase.
Michaela Löffler   +3 more
doaj   +1 more source

Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl [PDF]

open access: yesAtmospheric Chemistry and Physics, 2018
Chloromethane (CH3Cl) is an important provider of chlorine to the stratosphere but detailed knowledge of its budget is missing. Stable isotope analysis is a potentially powerful tool to constrain CH3Cl flux estimates.
F. Keppler   +11 more
doaj   +1 more source

Isotope Effects on Chemical Shifts in the Study of Intramolecular Hydrogen Bonds

open access: yesMolecules, 2015
The paper deals with the use of isotope effects on chemical shifts in characterizing intramolecular hydrogen bonds. Both so-called resonance-assisted (RAHB) and non-RAHB systems are treated. The importance of RAHB will be discussed.
Poul Erik Hansen
doaj   +1 more source

Temperature dependence of hydrogen isotope effect in LaNi5-H(D) system

open access: yesNuclear Analysis, 2023
To study inverse effect of hydrogen isotopes in LaNi5 for hydrogen isotope separation at ambient temperature, temperature dependence of hydrogen isotope effect in LaNi5-H(D) system was investigated in the temperature range -70 °C to 3 °C.
Weiwei Wang   +6 more
doaj   +1 more source

Bifunctional catalytic activity of anion-doped LaSrCoO4 for oxygen reduction and evolution reactions

open access: yesRoyal Society Open Science
Here, we synthesized Co-based, anion-incorporated‍ ‌R‌u‌d‌d‌l‌e‌s­d‌e‌n‌–‌Popper perovskite electrocatalysts (LaSrCoO4−x X y ) and compared their catalytic performances in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER).
Ittoku Nozawa, Hidehisa Hagiwara
doaj   +1 more source

Surface modification and sputtering erosion of iron and copper exposed to low-energy, high-flux deuterium plasmas seeded with metal species

open access: yesNuclear Materials and Energy, 2017
Four sets of targets were used in this study: (1) Fe targets surrounded with 304 type stainless steel composed of mid-Z elements: Fe, Cr, Ni, and Mn (designated as Fe[304SS] targets), (2) Fe targets surrounded with high-Z tungsten (designated as Fe[W ...
V.Kh. Alimov   +6 more
doaj   +1 more source

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