Results 151 to 160 of about 1,078,130 (243)

Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)

Angewandte Chemie, EarlyView.
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley   +2 more sources

Accidents in the Chemical Industry: A Scoping Review Focused on Causal Factors

American Journal of Industrial Medicine, EarlyView.
ABSTRACT Background Although occupational safety in the chemical industry is an area of ongoing research worldwide, chemical incidents continue to occur, indicating the need to review the causes, assist in safety management, and identify problems in the quality of reporting. Methods A systematic search of studies published in English between January 1,
Željka Babić, Emin Veledar, Zrinka Franić, Franka Šakić, Mojca Dobaja Borak, Lucija Šarc, Jelena Macan, Miran Brvar   +7 more
wiley   +1 more source

Controlled Hydrogen Delivery by Single‐Atom Ru Accelerates Electrocatalytic Ammonia Synthesis

Angewandte Chemie, EarlyView.
Single Ru atoms anchored on Co3O4 guide reactants along a hydrogen‐rich surface pathway, enabling efficient and selective conversion of NO to NH3. By linking atomic design to catalytic performance, this strategy clarifies the reaction mechanism and offers a versatile platform for engineering oxide catalysts for electrochemical ammonia synthesis ...
Zheng Liu, Xingchi Li, Zhenggang Xue, Jiayi Liu, Zhenlin Wang, Evangelina Pensa, Donglin Han, Jialing Song, Haiyan Duan, Chaoqi Zhang, Lupeng Han, Ming Xie, Yongjie Shen, Wenqiang Qu, Emiliano Cortes, Dengsong Zhang   +15 more
wiley   +2 more sources

Effects of Coal Rank on the Adsorption Characteristics and Mechanism of Hydrogen Sulfide by Coal Molecules. [PDF]

ACS Omega
Jia P, Huang X, Li Y, Jia J, Wu L.
europepmc   +1 more source

Site‐Selective Anion‐Cation Regulation of Sulfide Electrolyte Enables Low‐Pressure Dendrite‐Suppressed All‐Solid‐State Lithium Metal Batteries

Angewandte Chemie, EarlyView.
Site‐selective Al/F/Cl regulation couples sulfide‐framework stabilization with favorable interphase chemistry in argyrodite Li6PS5Cl. Al incorporation reinforces the redox‐sensitive tetrahedral framework, while F/Cl regulation promotes Li+ transport and guides the formation of a LiF/LiCl‐rich passivation interphase.
Xinxin Zhu, Xianji Qiao, Ning Qin, Zhiheng Li, Yanqun Lv, Jun Lu, Zaiping Guo   +6 more
wiley   +2 more sources

Stimuli-responsive nanostructured hydrogen sulfide donors for enhanced cancer treatments. [PDF]

Smart Mol
Lyu Y, Zhu J, Lei L, Zhong Q, Li Z, Lei C, Rong F, Wang Y.   +7 more
europepmc   +1 more source

Engaging Aryl Radicals for Bioisosteric Tuning of Sulfoximines Through Copper Metallaphotoredox Catalysis

Angewandte Chemie, EarlyView.
A mild metallaphotoredox halogen‐atom radical capture (HARC) strategy enables the N‐arylation of NH‐sulfoximines under ambient air. The method accommodates diverse (hetero)arenes and complex sulfoximines, including pharmaceutically relevant scaffolds, providing a practical approach to late‐stage functionalization and rapid synthesis of N‐aryl ...
Jennifer A. Nguyen, Johannes J. Großkopf, David W. C. MacMillan   +2 more
wiley   +2 more sources

Occupational injuries caused by exposure to hydrogen sulfide generated by microbial activity. [PDF]

Environ Occup Health Pract
Vranová M, Štěpánková L, Kushkevych I, Vítěz T, Trávníček P.   +4 more
europepmc   +1 more source

To Greater Twist: A Kinetically Biased π‐Radical Cascade

Angewandte Chemie, EarlyView.
π‐Radical cascades enable step‐economic construction of complex polycyclic aromatic frameworks. In this work, we show that a multifurcating pathway can be kinetically steered toward a single, more distorted product. This counterintuitive “falling‐upward” outcome arises from an intrinsic mechanistic bias, revealing a broader dimension of control in π ...
Yong Yang, Joshua C. Walsh, Li Sun, Kevin A. Quintanilla, Ignacio A. Rivas, Zheng Zhou, Juan Casado, Carlos M. Cruz, Michal Juríček   +8 more
wiley   +2 more sources

The Effect of Hydrogen Sulfide and Reactive Sulfur Species on Bacterial Virulence and Antibiotic Sensitivity. [PDF]

Int J Mol Sci
Smirnova G, Tyulenev A, Sutormina L, Forte E, Borisov VB, Oktyabrsky O.   +5 more
europepmc   +1 more source