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Unveiling active sites and the cooperative role of non-thermal plasma and copper-zinc catalysts in the hydrogenation of CO<sub>2</sub> to methanol. [PDF]

open access: yesNat Catal
Xu S   +29 more
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Hydrogenative Cyclopropanation and Hydrogenative Metathesis

Angewandte Chemie International Edition, 2019
AbstractThe unusual geminal hydrogenation of a propargyl alcohol derivative with [CpXRuCl] as the catalyst entails formation of pianostool ruthenium carbenes in the first place; these reactive intermediates can be intercepted with tethered alkenes to give either cyclopropanes or cyclic olefins as the result of a formal metathesis event.
Sebastian Peil   +3 more
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