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Standardization transformation of C-lignin to catechol and propylene. [PDF]
Shen X +9 more
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Reversible lignin stabilization in traditional aqueous pulping conditions using boric acid
Luterbacher J +10 more
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Hydrogenolysis of methyltetrahydrofurane on platinum
Applied Catalysis, 1984Abstract The hydrogenolysis of methyltetrahydrofuran on supported platinum of high and low dispersion (EUROPT-1 and sintered EUROPT-1) as well as on platinum black was studied in a flow reactor. Based on the variation of activity and selectivity with time on stream, space velocity and temperature, the different behaviour of the three catalysts is ...
U. Gennari, R. Kramer, H.L. Gruber
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Catalytic Hydrogenolysis of Glycerol
2008Rhodium-based catalysts were evaluated for the hydrogenolysis of glycerol. The study was focused on the influence of pH and metal additives on catalyst activity and selectivity. Under basic conditions, 1,2-PDO was formed with high selectivity (> 90%). Traces of acetol and ethylene glycol were detected and lactic acid was observed at high pH.
Besson, M. +5 more
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Tetrahedron, 1986
Abstract On catalytic hydrogenation over Pd-C under normal conditions cubane ( 10 ) takes up 3 mol of hydrogen in a few hours. Bicyclo[2.2.2] octane ( 13 ) is formed as the main product, and tetracyclo[4.2.0.0 2,5 .0 3,8 ]octane (11, secocubane) and tricyclo[4.2.0.0 2,5 ]octane ( 12 ,nortwistbrendane) have been identified as intermediates.
Reinhard Stober, Hans Musso, Eiji Ōsawa
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Abstract On catalytic hydrogenation over Pd-C under normal conditions cubane ( 10 ) takes up 3 mol of hydrogen in a few hours. Bicyclo[2.2.2] octane ( 13 ) is formed as the main product, and tetracyclo[4.2.0.0 2,5 .0 3,8 ]octane (11, secocubane) and tricyclo[4.2.0.0 2,5 ]octane ( 12 ,nortwistbrendane) have been identified as intermediates.
Reinhard Stober, Hans Musso, Eiji Ōsawa
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Hydrogenation and Hydrogenolysis
ChemInform, 2006AbstractFor Abstract see ChemInform Abstract in Full Text.
Ferenc Joo, Agnes Katho
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Production of Biobutanediols by the Hydrogenolysis of Erythritol
ChemSusChem, 2012AbstractThe hydrogenolysis of erythritol using an Ir–ReOx/SiO2 catalyst was performed for the production of butanediols, which are widely used as a raw material of polymers. The activity and selectivity to butanediols on Ir–ReOx/SiO2 was much higher than that on conventional hydrogenolysis catalysts.
Yasushi Amada +2 more
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HYDROGENOLYSIS OF CARBOHYDRATES. X. HYDROGENOLYSIS OF (±)-EPI-INOSOSE-2
Canadian Journal of Chemistry, 1964not available
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Hydrogenolysis of Carboxylic Ortho Esters
The Journal of Organic Chemistry, 2022It is demonstrated for the first time that carboxylic ortho esters may be reduced to acetals using hydrogen as the reducing agent. Hydrogenolysis was performed under mild conditions over commercially available hydrogenation catalysts (5% Pd/C and 5% Pt/C).
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The Catalytic Hydrogenolysis of Benzylamine Derivatives
Tetrahedron, 1973Abstract The hydrogenolysis of optically active ethyl 2-amino-2-phenylpropionate ( I ), its N-methyl ( II ), and N,N-dimethyl ( III ) derivatives was studied using Raney Ni and Pd as the catalysts. The Raney Ni catalysed hydrogenolysis of II and III , as well as the reaction catalysed by Pd, occurred predominantly with inversion of configuration ...
Y. Sugi, S. Mitsui
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