Results 191 to 200 of about 93,640 (301)

Substituent‐Controlled Ring Opening of 1‐Substituted Benzocyclobutenes: Electronic Structure and Diradical Character of Ortho‐Quinodimethane Intermediates

open access: yesChemistry – A European Journal, EarlyView.
Experimental and computational studies elucidate how the electronic nature of substituents controls the ring‐opening temperature and diradical character of 1‐substituted benzocyclobutenes, enabling the rational design of o‐quinodimethane‐based synthetic transformations.
Magali Dallegre   +8 more
wiley   +1 more source

High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao   +8 more
wiley   +1 more source

Bis(trifluoromethyl)disulfide and the EtP4 Phosphazene Base—Formation of a Bench‐Stable [EtP4SCF3]+[SCF3]− Salt

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of a bench‐stable trifluoromethylthiolate‐substituted phosphazenium salt is reported. Reaction of bis(trifluoromethyl)disulfide with the EtP4 phosphazene base furnishes this salt in quantitative yield. The compound features a unique trifluoromethylthiolate‐iminium motif and allows for functionalization of both trifluoromethylthiolate ...
Lukas Hartmann   +6 more
wiley   +1 more source

Bioresponsive pseudoGlucosinolates (psGSLs) Release Isothiocyanates (ITCs) in the Presence of Nitroreductases

open access: yesChemistry – A European Journal, EarlyView.
This work introduces the concept of pseudoglucosinolates (psGSLs) and reports the synthesis and evaluation of nitroreductase‐responsive psGSLs. These compounds represent a complementary prodrug strategy to natural glucosinolates (GSLs) for the controlled release of isothiocyanates (ITCs), enabling bio‐responsive protein labeling, as demonstrated in ...
Claire C. Jimidar   +13 more
wiley   +1 more source

Waste activated sludge high‐rate treatment of septage: Biodegradability studies and contact phase trials towards a cleaner environment

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The waste activated sludge high‐rate (WASHR) process, developed in our previous study, is used for septic wastewater treatment. This high‐rate contact stabilization pre‐treatment uses typical waste streams found in wastewater treatment plants to reduce a portion of the loadings on the main treatment trains.
Arman Shirali   +2 more
wiley   +1 more source

Synthesis, characterization, and performance of x_MoO3/Z‐22 and x_MoO3/MMP catalysts for biodiesel production

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Methyl transesterification of soybean oil using heterogeneous catalysts for biodiesel production. Abstract The growing global demand for renewable fuels has driven the search for efficient catalysts in biodiesel production. This study presents the synthesis and characterization of x_MoO3/Z‐22 and x_MoO3/MMP heterogeneous catalysts, and evaluates the ...
André Miranda da Silva   +4 more
wiley   +1 more source

Optimization of a reactor for biostimulant production with emphasis on the economic aspects of hydrolysis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Biostimulants are increasingly used in agriculture to promote plant growth, improve stress tolerance, and support sustainable farming practices. One common method of production is chemical hydrolysis of protein‐rich waste, such as tannery by‐products, offering an economical and eco‐friendly alternative to conventional raw materials.
Karel Kolomazník   +3 more
wiley   +1 more source

Recreational Drug Use at a Music Festival: A Dual Approach Using Hair Biomarkers Analysis and Participant Self‐Reported Drug Use

open access: yesDrug Testing and Analysis, EarlyView.
Combined self‐report and hair analysis in festival attendees (n = 249) revealed substantial discrepancies in drug use reporting, particularly for stimulants and dissociatives. This integrated approach enhances detection of poly‐drug use and provides a more reliable basis for monitoring and harm‐reduction strategies.
A. Y. Simão   +4 more
wiley   +1 more source

Dynamic Covalent Chemistry Enables Self‐Healing and Compatibilization in Polypropylene Composites

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A high‐performance polypropylene insulation material is created through dynamic covalent crosslinking. It achieves exceptional dielectric properties, autonomous self‐healing, and easy recycling, offering a sustainable solution for future HVDC transmission systems.
Hongzhe Zhang   +3 more
wiley   +1 more source

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