A combination of ab initio molecular dynamics simulations and density functional theory calculations clarifies the pH‐dependent origin of the selectivity of nitrate reduction on Cu(100). ABSTRACT We investigate the nitrate reduction reaction (NO3 RR) on the Cu(100) surface using grand‐canonical density functional theory (GC‐DFT) under constant ...
Ebrahim Tayyebi, Kai S. Exner
wiley +2 more sources
Engineering Enantiocomplementary Protoglobins for Stereoconvergent Construction of <i>N</i>-Alkylated α-Aminoketones. [PDF]
Qin ZY +8 more
europepmc +1 more source
Hepatocellular carcinoma (HCC)‐derived extracellular vesicles (EVs) enrich the metabolic enzyme ATP‐citrate lyase (ACLY). EV‐transferred ACLY enhances palmitate biosynthesis, increases the S‐palmitoylation and stability of multiple immune checkpoint proteins, augments the cellular immunosuppressive activity, and ultimately accelerates the malignant ...
Zhijun Liu +11 more
wiley +1 more source
One-Step Rh-Catalyzed Atom-Economical Cyclization of Acetophenones and Methyl Propiolate Affording Isoquinoline Derivatives. [PDF]
Zeng F +8 more
europepmc +1 more source
Covalent Reprogramming of Kinase Binders to Modulate Protein Abundance
Electrophilic remodeling of a broad‐spectrum kinase binder reveals how subtle chemical changes reprogram protein fate. An acrylamide analog of a multi‐kinase binder selectively stabilizes Aurora kinase A (AURKA) by suppressing its ubiquitination, while a short‐linker variant converts this stabilizer into a degrader.
Chen Mozes +4 more
wiley +1 more source
CRISPLD2 protects against liver inflammation and fibrosis via GRP78 to repress HMGB1/TLR4 axis-mediated STING palmitoylation. [PDF]
Zhang H +5 more
europepmc +1 more source
Corn response to biological products and a nitrification inhibitor
Abstract Atmospheric nitrogen (N2) is converted into ammonia (NH3), a form that plants can use, through biological nitrogen (N) fixation by various microorganisms and bacterial genera. This study assessed the field performance of three biological N‐fixing products, or biostimulants (BS), including Gluconacetobacter diazotrophicus (BS1), Klebsiella ...
Rose M. Paul +3 more
wiley +1 more source
Nitrous Oxide Production and Hydroxylamine Accumulation in a Partial Nitritation Sequencing Batch Reactor: Comparison of Different Operational Strategies. [PDF]
Olmo L, Carrera J, Pérez J.
europepmc +1 more source
Revealing the Mechanism of TEMPO-Hypervalent Iodine(III) Oxidation of Alcohols. [PDF]
Bingham M +6 more
europepmc +1 more source
TiCl<sub>3</sub>-Mediated Reductive Aminohydroxylation of Alkenes to (Benzo)Furo[3,2-<i>b</i>]Indolines. [PDF]
Boyarskaya D +4 more
europepmc +1 more source

