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A spectroscopic probe for hypochlorous acid detection

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2022
A spectroscopic probe CMBT was synthesized and characterized. CMBT showed the specific recognition for HClO based on the turn-on blue fluorescence and naked-eye change from pink to colorless. NMR, IR, HRMS-ESI, and spectral analysis suggested that colorimetric and fluorescent change of CMBT to HClO originated from the conversion of CMBT to starting ...
Dan Wang, Ning An, Yunling Gao, Hui Zhao
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THE ACTION OF HYPOCHLOROUS ACID ON ARYLIDENECYANOACETIC ACIDS

Canadian Journal of Research, 1932
The action of hypochlorous acid on p-methoxybenzylidenecyanoacetic acid has been found to produce p-methoxyphenylacetic acid. When treated in the same way, o-methoxybenzylidene-, veratrylidene- and piperonylidenecyanoacetic acids give the corresponding substituted phenylacetic acids in moderately good yields.
John A. McRae, Clarence Yardley Hopkins
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Reactions of pholasin with peroxidases and hypochlorous acid

Free Radical Biology and Medicine, 2000
The ability of myeloperoxidase (MPO) and horseradish peroxidase (HRP) to induce chemiluminescence (CL) in Pholasin (Knight Scientific, Plymouth, UK), the photoprotein of the Common Piddock Pholas dactylus, was studied. The oxidation of Pholasin by compound I or II of HRP induced an intense light emission, whereas native HRP showed only a small effect ...
Jürgen Arnhold   +4 more
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Immunoglobulin cleavage by hypochlorous acid treatment

Clinica Chimica Acta, 1995
IgA, IgG and IgM were cleaved by hypochlorous acid treatment. The apparent calculated molecular masses of three polypeptides obtained from IgA were 81.1. 25.8 and 13.9 kDa. The amounts of released IgA fragments were proportional to the amount of HOCl employed.
Ibeth Guevara   +2 more
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The Reaction of Hemoproteins with Hypochlorous Acid

Chemistry Letters, 2008
Abstract We have studied absorption spectral changes and heme modifications in the reaction of horseradish peroxidase (HRP), myoglobin (Mb), or bovine liver catalase (BLC) with hypochlorous acid (HOCl). Under acidic condition, HOCl is easily released from an FeIII–HOCl complex.
Junko Inoue   +3 more
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Effects of hypochlorous acid on unsaturated phosphatidylcholines

Free Radical Biology and Medicine, 2001
Effects of hypochlorous acid and of the myeloperoxidase-hydrogen peroxide-chloride system on mono- and polyunsaturated phosphatidylcholines were analyzed by means of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS).
Jürgen Arnhold   +4 more
openaire   +2 more sources

THE DECOMPOSITION OF HYPOCHLOROUS ACID

Canadian Journal of Chemistry, 1952
The rate of decomposition of hypochlorous acid has been measured in aqueous solution in the presence of much sodium hypochlorite. The rate is nearly independent of the hypochlorite concentration, and proportional to the square of the hypochlorous acid concentration. Hence the mechanism proposed is[Formula: see text][Formula: see text]The first step is
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Photocatalytic Production of Hypochlorous Acid over Pt/WO3 under Simulated Solar Light

ACS Sustainable Chemistry and Engineering, 2020
The production of hypochlorous acid (HClO) over a visible-light active photocatalyst was achieved for the first time in an aqueous solution of NaCl under simulated solar light.
Rui Pang   +3 more
semanticscholar   +1 more source

Facile and Highly Selective Ratiometric Fluorescence Probe Based on Benzo[5]helicene for the Detection of Hypochlorous Acid

, 2020
In physiological processes, hypochlorous acid can regulate in vitro signaling molecules as one kind of reactive oxygen species (ROS).
Yi-Meng Duan   +7 more
semanticscholar   +1 more source

Hypochlorous acid reversibly inhibits caspase-3: a potential regulator of apoptosis

Free radical research, 2020
Caspase-3 is involved in apoptosis. Here, we examine whether hypochlorous acid (HOCl), a final product of myeloperoxidase (MPO), is a modulator of caspase-3 at relatively low concentrations and also its application on metaphase II mouse oocytes.
R. Jeelani   +7 more
semanticscholar   +1 more source

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