Results 161 to 170 of about 28,189 (250)

Simultaneous Electronic and Crystallographic Modulation of Cs3Bi2Br9 by Single‐Element Sn Substitution for Enhanced CO2 Photoreduction

open access: yesAdvanced Energy Materials, EarlyView.
Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor   +7 more
wiley   +1 more source

Hole‐Activated Lattice Oxygen Enables Pt‐Free Propane Dehydrogenation by Eliminating the Hydrogen Recombination Bottleneck

open access: yesAngewandte Chemie, EarlyView.
Trace Mg doping into gallia–alumina generates hole‐type oxygen species that accelerate hydrogen recombination, eliminating the need for Pt promotion. The fully oxide‐based catalyst resists sintering under repeated regeneration, outperforming benchmark PtSn and CrOx catalysts with exceptional stability over 30 dehydrogenation–regeneration cycles ...
DongHwan Oh   +8 more
wiley   +2 more sources

Electric Double Layer Engineering Induces O‐Down Interfacial Water Reorientation for Efficient and Long‐Term Seawater Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
The additive EDTMPS inhibits hydroxides deposition by chelating with Ca2+/Mg2+. It also disrupts the hydrogen bond network of interfacial water and expands the thickness of electric double layer, promoting more free water to flip into adsorbable O‐down configuration.
Tongzhou Li   +7 more
wiley   +1 more source

Beyond Canonical CO Oxidation: Structural and Evolutionary Insights Into a Non‐Canonical Carbon Monoxide Dehydrogenase

open access: yesAngewandte Chemie, EarlyView.
Clade B carbon monoxide dehydrogenases (CODHs) remain enigmatic, diverging from canonical CODHs in structure and function. Here, we present the first characterization of Ruminococcus flavefaciens CODH (RfCODH), revealing occluded substrate pathways and attenuated CO oxidation activity.
Maximilian Böhm   +6 more
wiley   +2 more sources

Solid–liquid equilibria in the LiOH–ethanol–water system: Solubility measurements and thermodynamic modeling

open access: yesAIChE Journal, EarlyView.
Abstract The demand for LiOH is driven by the growth of the electric vehicle industry. Evaporative crystallization of LiOH·H2O is energy intensive, whereas ethanol‐based antisolvent crystallization has emerged as a more sustainable alternative. From a process design perspective, the crystallization yield depends on the ethanol dosage, and thermodynamic
Xiaoqi Xu   +3 more
wiley   +1 more source

Direct Solar Power‐Driven Durable Ammonia Electrosynthesis From Nitrate Under Fluctuating Voltage Conditions

open access: yesAngewandte Chemie, EarlyView.
Isolated Sn sites on Cu(111) induce a highly asymmetric charge distribution, which promotes water dissociation, accelerates key intermediate hydrogenation, and suppresses competing hydrogen evolution. As a result, SnCu111 delivers NH3 Faradaic efficiencies above 90% over an 800 mV potential window and enables stable direct solar power‐driven NH3 ...
Xiaokang Wang   +8 more
wiley   +2 more sources

Predicting Catalyst Performance From Pt/CeO2 Redispersion Kinetics

open access: yesAngewandte Chemie, EarlyView.
Unravelling kinetics of dynamic structural changes in catalysts is the key to predicting their catalytic properties. ETEM experiments reveal a continuous decrease in Pt particle size on cube‐shaped CeO2 under oxidizing conditions, changing from large nanoparticles to highly dispersed species.
Florian Maurer   +11 more
wiley   +2 more sources

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