Results 181 to 190 of about 28,189 (250)

Adaptive Hydrogenation of Alkynes Using CO as a Molecular Trigger to Selectively Produce Alkanes or Z‐Alkenes

open access: yesAngewandte Chemie, EarlyView.
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai   +7 more
wiley   +2 more sources

Natural Sunlight IR‐Driven Highly Efficient Synthesis of Acetaldehyde From Bioethanol Over Cu/Fe2O3

open access: yesAngewandte Chemie, EarlyView.
This work reports a Cu/Fe2O3 catalyst for the conversion of bioethanol into valuable acetaldehyde and green hydrogen under both infrared (IR) light and natural sunlight. This IR‐driven system sets a new performance benchmark, with TON and initial TOF enhanced by at least one order of magnitude, enabled by a constructed IR photon‐to‐phonon channel and ...
Xiyi Li   +10 more
wiley   +2 more sources

Ion Transfer During Ionomer Contact Electrification: Binding Affinity Controls Charging

open access: yesAngewandte Chemie International Edition, EarlyView.
The binding affinity between mobile ions and fixed ionomer groups determines the amount of charge transferred during contact electrification. Ionomers with a series of mobile alkali cations as well as mobile anions establish a clear ordering in charge transfer, where higher interaction strength leads to lower charge transfer.
John R. Hoffman   +2 more
wiley   +1 more source

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