Results 241 to 250 of about 88,261 (305)

Engineering Spin State of Ni Single‐Atoms to Enhance Electrocatalytic Activity of Sulfur Conversion in Lithium–Sulfur Batteries

Carbon Energy, EarlyView.
Ni SACs with high‐spin state show strong catalytic activity toward lithium polysulfides (LPSs), whereas the Ni SACs with low‐spin state have strong adsorption capacity for LPSs. Therefore, the preparation of Ni SACs with an intermediate spin state by controlling pyridinic N and pyrrolic N enables an excellent balance between the adsorption and ...
Mengyang Li, Guiqiang Cao, Yiming Qi, Chenyang Hou, Xuexia Song, Ruixian Duan, Huijuan Yang, Yifan Li, Xiaorui Chen, Zongnan Lv, Qinchuan Chen, Yitong Yuan, Guohua Liu, Yuhui Xu, Jingjing Wang, Wenbin Li, Xifei Li   +16 more
wiley   +1 more source

Boosting Electron‐Hole Charge Separation in CO2 Photoreduction through Fluoroporphyrin‐Linked Nickel(II)‐Acetylide Frameworks

Carbon Energy, EarlyView.
A NiII‐acetylide framework, H2TFPP‐Ni‐AF, demonstrates outstanding photocatalytic CO2 reduction performance: 13.16 mmol h−1 g−1 of CO with 97.9% selectivity. Synergistic interactions, including d‐p orbital hybridization within NiII‐bis(acetylide) moieties ( − C ≡ C−NiII(PBu3)2 − C ≡ C − ) and the efficient charge transport afforded by π‐conjugated ...
Lifen Chen, Lian Duan, Yidi Wang, Yasuteru Shigeta, Kowit Hengphasatporn, Linli Xu, Wai‐Yeung Wong   +6 more
wiley   +1 more source

Two‐Step Synthesis of a Chiral Fluorinated Alcohol With Silica‐Supported Enzyme RrADH in Batch and Continuous Flow Mode

Chemistry – A European Journal, EarlyView.
A two‐step process was transferred from batch to flow mode for the synthesis of (R)‐2‐fluoro‐1‐phenylethanol as a benchmark, consisting of a decarboxylative fluorination in aqueous media, followed by an enantioselective biocatalytic reduction of the prochiral intermediate with RrADH immobilized on silica supraparticles.
Egzon Cermjani, Greta Nölke, Stefano Di Fiore, Christoph Deckers, Doris Hanselmann, Bettina Herbig, Susanne Wintzheimer, Thomas H. Rehm   +7 more
wiley   +1 more source

Boric Acid Post‐Modified [Al]ZSM‐5 Zeolites: Properties, Acidity, and Ethanol/Ethene Conversion

Chemistry – A European Journal, EarlyView.
The modification of MFI zeolites with boric acid leads to the formation of framework boron, unstable surface species, and unbound deposits. Relevant BAS for catalysis and access to pores are strongly reduced. The boric acid is removed upon converting C1 or C2 alcohols and ethene. ABSTRACT The effect of boric acid post‐modification on [Al]ZSM‐5 zeolites
Zheng Li, Daniel Dittmann, Dennis Strassheim, Michael Dyballa   +3 more
wiley   +1 more source

Precipitation of niobic acid from potassium niobate in sulphuric acid solution: A route to niobium oxide

The Canadian Journal of Chemical Engineering, EarlyView.
Graphical abstract illustrating the niobic acid precipitation process applied and the product obtained. Abstract This study investigates the precipitation of niobic acid (Nb2O5.nH2O) from potassium niobate solution with addition of sulphuric acid, and its subsequent thermal conversion into niobium oxide (Nb2O5). Thermodynamic modelling with PHREEQC and
Cássia R. Souza, Gabriela C. Silva, Isabel P. Silva, Frederico M. Penha, Sônia D. F. Rocha   +4 more
wiley   +1 more source

Experimental methods in chemical engineering: Atomic absorption spectrometry—AAS

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Elements absorb electromagnetic radiation (light) of a specific wavelength in proportion to the number of atoms in its path. As the atoms absorb this light energy, electrons rise from the ground state to an excited state. In atomic absorption spectrometry (AAS), high temperatures produce clouds of atoms from the sample (atomization) and ...
Emily Cintia Tossi de A. Costa, Jildimara de Jesus Santana, Viviane de Oliveira Campos, Felipe Fernandes Barbosa, Gregory S. Patience   +4 more
wiley   +1 more source

The Cathodic Deposition Coupled With Ion Exchange Technology Enables the Recycling of Radioactive Molten Salts

CleanMat, EarlyView.
Developed an integrated electrolysis‐molecular sieve adsorption system to remove fission products from radioactive molten salts in spent fuel dry reprocessing. This approach selectively extracts hazardous fission products, resolves diminished current efficiency during electrolysis termination, and enables direct solidification without supplementary ...
Xiaoxue Deng, Yingcai Wang, Xinbo Zhang, Zhibin Zhang, Yunhai Liu   +4 more
wiley   +1 more source

IODP Exp. 325 Great Barrier Reef Environmental Changes (GBREC) QAQC - Documentation - Analytics [PDF]

, 2010
Schnieders, L.
core  

Crystallization of Cathode Active Material Precursors from Tartaric Acid Solution

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
This work investigates a novel approach for closing the gap between recycling and production of lithium‐ion battery cathode material. The new concept is based on antisolvent crystallization of metal carboxylates, which can be directly used as precursors in production of cathode material.
Chunyan Ma, Mona Mohamoud, Tiaan Punt, Jinlong Li, Michael Svärd, Kerstin Forsberg   +5 more
wiley   +1 more source