Results 131 to 140 of about 124,234 (235)

Durable Fuel Cell Cathode Enabled by Pt Embedded Nanoscale Carbon Network via a Scalable Process

open access: yesCarbon Energy, EarlyView.
Platinum nanoparticles embedded nanoscale carbon network (Pt‐e‐Cn) are developed via a scalable flame spray pyrolysis process. Proton exchange membrane fuel cells (PEMFC) employing mesoporous Pt‐e‐Cn cathode electrocatalysts exhibit exceptional durability without compromising performance.
Suriya Venkatesan   +10 more
wiley   +1 more source

Synthesis of the Phospha‐Wittig Reagent Me3P = P(C2F5) and Generation of a Phospanyl‐Wittig Derivative Me3P = C(CF3)P(C2F5)F

open access: yesChemistry – A European Journal, EarlyView.
The first example of a simple alkylated phosphinidene‐adduct (“phospha‐Wittig”) is reported. The synthesis of Me3PPC2F5 was enabled through reaction of the cyclotetraphosphane (PC2F5)4 with PMe3. The phosphanyl‐functionalized Wittig reagent Me3PC(CF3)P(C2F5)F was prepared by treating the diphosphane P2(C2F5)4 with PMe3.
Lukas Hartmann   +7 more
wiley   +1 more source

Bond Formation: Shaken, Not Stirred

open access: yesChemistry – A European Journal, EarlyView.
Shaking of seismo‐molecules efficiently transforms kinetic energy into storable chemical potential, unlocking high‐utility Gibbs free energy. This innovative mechanism pioneers uncharted scientific frontiers, introducing fascinating phenomena like seismochemistry, seismochromism, and seismofluorescence that redefine the boundaries of molecular ...
Alexander D. Q. Li
wiley   +1 more source

Methanol With Increased Water Content in Internal Combustion Engines

open access: yesChemie Ingenieur Technik, EarlyView.
This study investigates the potential to improve overall Well‐to‐Wheel efficiency by using low‐purity methanol from synthesis of hydrogen and furnace gas as CO2‐source. Combustion efficiency is comparable to pure methanol, while distillation energy could be saved.
Maximilian Dobberkau   +3 more
wiley   +1 more source

Analysis of Radial Heat Transfer in Cooled Fixed‐Bed Reactors by One‐ and Two‐Dimensional Models

open access: yesChemie Ingenieur Technik, EarlyView.
Exothermic fixed‐bed reactors are analyzed using 1D and 2D models. Radial temperature profiles from the 2D model enable optimization of the 1D approach via adjusted overall heat transfer coefficient. Derived correlations improve prediction accuracy, whereas thermal runaway behavior and model sensitivity are evaluated. ABSTRACT Exothermic reactions in a
Cora Bischoff, Andreas Jess
wiley   +1 more source

Laminar Burning Velocity of Ammonia‐Hydrogen Mixtures Predicted by Machine Learning

open access: yesChemie Ingenieur Technik, EarlyView.
Ammonia–hydrogen blends aid defossilization, but slow combustion kinetics require complex modeling. Although chemical kinetic modeling is computationally expensive, machine learning surrogates offer fast predictions. This study trained GPR, DT, and ANN models on 1445 experimental points.
Georg Klepp   +2 more
wiley   +1 more source

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