Intramolecular asymmetric propargylation of esters and imides: C-H functionalisation enables stereocontrolled access to UCS1025A. [PDF]
Corcoran JC +4 more
europepmc +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Atomically Dispersed Cobalt on Ionic Carbon Nitrides for Selective and Efficient Nitrate Electroreduction to Ammonia. [PDF]
Gao N +14 more
europepmc +1 more source
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai +7 more
wiley +2 more sources
On the Question of the Full Selective Synthesis of Potentially Bioactive of 2-(<i>tert</i>-Butyl)-3-hydroxy-7-2,3-dihydro-1<i>H</i>-pyrrolo[3,4-c]pyridin-1-ones and Their Derivatives: Experimental and DFT Computational Study. [PDF]
Ciechańska M +4 more
europepmc +1 more source
Zwei fluorierte Ether aus dem Bereich der Wärmeträgerflüssigkeiten werden als Co‐Diluenten in lokal hochkonzentrierten Elektrolyten für lithiummetallbasierte Batterien eingesetzt. Die ternäre Diluentenmischung erhöht die Ionenmobilität, senkt die Überspannung und verbessert so coulombische Effizienz und Lebensdauer der Zelle bei hohen Stromdichten, was
Dominik Weintz +11 more
wiley +1 more source
Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley +2 more sources
Band Gap Tuneability in Antiperovskite-Based Nitrides AE<sub>3</sub>PnN and Imides AE<sub>5</sub>Pn<sub>2</sub>(NH)<sub>2</sub> (AE = Ca, Sr; Pn = As, Sb, Bi). [PDF]
Chau TG +9 more
europepmc +1 more source
Revisiting Coulombic Efficiency Paradigm: Electrolyte Additive Design for Lithium Metal Batteries
Coulombic efficiency (CE) is a key metric for screening advanced electrolyte formulations for rechargeable batteries. Combined with interphasial characterizations, statistical analyses of CE data uncover the synergistic interaction between fluorinated additives and salt anions, enabling more precise correlations of chemical functionalities with ...
Qixin Wang +16 more
wiley +2 more sources
Green Supercritical CO<sub>2</sub> Ion-Exchange Strategy for Cation Engineering in Polyheptazine Imides Towards Efficient Photoreduction CO<sub>2</sub> to C<sub>2</sub>H<sub>4</sub>. [PDF]
Peng X, Du L, Fu G, Zhang S, Ma J.
europepmc +1 more source

