Results 121 to 130 of about 14,359 (248)

Stereodynamic Helicenes for Chirality Sensing and Enantiomeric Assay through Diastereomeric Helical Enrichment. [PDF]

JACS Au
Sarkar D, Bag S, Jana K, Sujith M, Mori T, Suresh CH, Moorthy JN.   +6 more
europepmc   +1 more source

Proton‐Switching Regulates Interfacial Iodine Chemistry for Long‐Life Zinc–Iodine Batteries

Angewandte Chemie, EarlyView.
A proton‐switchable imine‐linked framework is developed to dynamically regulate interfacial iodine chemistry in aqueous Zn–I2 batteries, where reversible protonation/deprotonation switches the host affinity between iodide and polyiodide species. This state‐dependent regulation suppresses shuttle‐induced side reactions while preserving fast iodine redox
Feifei Wang, Guoqin Liu, Yuhang Zhuang, Peng Zhang, Zhengwei Li, Songshan Bi, Ahmad Bagheri, Angelika Wrzesińska‐Lashkova, Neda Kargarfard, Peyman Rostami, Yana Vaynzof, Bernd Plietker, Mingchao Wang, Ali Shaygan Nia, Xinliang Feng   +14 more
wiley   +2 more sources

Light-Driven Epimerization: Diastereoconvergent Synthesis of [¹²C, ¹³C] β^2,3-Amino Acids. [PDF]

Angew Chem Int Ed Engl
Zhang L, Sun Y, Yu H, Zhu Y, Zhai R, Li P, Yang P, Tang B.   +7 more
europepmc   +1 more source

Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity‐Matched N‐Radical Cations

Angewandte Chemie, EarlyView.
Highly electrophilic N‐radical cations enable efficient and selective H‐atom transfer (HAT) of unprotected amines. In this exceedingly practical strategy, simple CuCl catalyzes an interrupted Hofmann–Löffler–Freytag (HLF) reaction to afford δ desaturated amines, aza‐heterocycles, and C─H aminated alkanes without protecting groups.
Pavitra Laohapaisan, Ross M. Dare, Meredith L. Rudich, Jacob J. A. Garwood, Siyuan Gong, R. Thomas Simons, David A. Nagib   +6 more
wiley   +2 more sources

Construction of C═N/C─N Bonds From N₂ Driven by Sheath Electric Field at Nonaqueous Microdroplet Interfaces. [PDF]

ChemSusChem
Wang H, Wang Y, Bao R, Fu D, Liu J, Jiao Y, Wang S, Shen B, Zhang X, Xu C, Han Y.   +10 more
europepmc   +1 more source

Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis

Angewandte Chemie, EarlyView.
The cooperative reactivity characteristic of molecular dinuclear nickel complexes is transferred to mesoporous silica through a systematic immobilization strategy. The resulting material preserves the key features of the bimetallic motif within a robust heterogeneous framework, demonstrating how molecular design principles can be translated into well ...
Jitpisut Poolwong, Adrian Jenner, Eric Juriatti, Mustafa Turan, Manfred Manßen   +4 more
wiley   +2 more sources

Aktivierung von Metallkomplexen durch Ultraschallwellen für eine gezielte Krebstherapie

Angewandte Chemie, EarlyView.
Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean, Nicolás Montesdeoca, Gilles Berger, Johannes Karges   +3 more
wiley   +1 more source

Metal-free sustainable synthesis of oximes and hydrazones from benzyl alcohol and benzylamine. [PDF]

RSC Adv
Devgunde RB, Rupanawar BD, Rupnavar PB, Waghmode SB.   +3 more
europepmc   +1 more source

RETRACTED: Melendez et al. Experimental and DFT Study of the Photoluminescent Green Emission Band of Halogenated (-F, -Cl, and -Br) Imines. <i>Molecules</i> 2019, <i>24</i>, 3304. [PDF]

Molecules
Melendez FJ, Castro ME, Portillo-Moreno O, Hernández-Téllez G, Moreno-Morales GE, Gutiérrez-Argüelles D, Palomino-Merino R, Rubio-Rosas E, Gutiérrez-Pérez R.   +8 more
europepmc   +1 more source

Semiconducting Covalent Organic Frameworks Based on Spin‐Delocalized Trioxotriangulene Neutral Radicals

Angewandte Chemie, EarlyView.
Imine‐linked 2D covalent organic frameworks incorporating delocalized trioxotriangulene (TOT) neutral radicals were synthesized through complementary routes. Direct incorporation of an amine‐functionalized TOT radical yields a highly crystalline, porous framework (TOT‐COF‐H) with intrinsic semiconducting behavior (σRT = 1.2 × 10−4 S cm−1) and a narrow ...
Paula Escamilla, Sara Trigo‐Pérez, Rafael Ramos, Ricardo Ortiz, Manuel Vilas‐Varela, Diego Peña, Manuel Melle‐Franco, Francisco Rivadulla, Manuel Souto   +8 more
wiley   +2 more sources