Results 241 to 250 of about 64,220 (327)

Unlocking the Continuous Flow Asymmetric Hydrogenation of Olefins Through the Development of a Non‐Deactivating Immobilized Iridium Catalyst

open access: yesAngewandte Chemie, EarlyView.
We have developed stable, robust, and reusable heterogeneous metal catalysts for an efficient continuous flow asymmetric hydrogenation (AH) of a variety of olefins, far beyond the typical benchmark AH. The products are produced continuously over long periods of time with high catalytic performance (up to 99% ee).
Jorge Faiges   +5 more
wiley   +2 more sources

Photoinduced Ring‐Opening Polymerization of N‐Carboxyanhydrides for the Preparation of Cross‐Linked Polypeptide Gels

open access: yesAngewandte Chemie, EarlyView.
We employ a photochemical approach for ring‐opening polymerization (ROP) of α‐amino acid N‐carboxyanhydride (NCA) monomers to prepare covalently cross‐linked synthetic polypeptide gels using a photobase and light, which offers significant advantages in the synthesis of polypeptides and holds great potential for applications requiring spatial and ...
Ana Kočman   +3 more
wiley   +2 more sources

Umpolung Activation of Bicyclobutanes via N-Heterocyclic Carbene Catalysis. [PDF]

open access: yesAngew Chem Int Ed Engl
Chang YC   +5 more
europepmc   +1 more source

Dynamic Confinement Approach for High Metal Loading Single‐Atom Catalysts Based on Covalent Organic Frameworks

open access: yesAngewandte Chemie, EarlyView.
We introduced a new synthetic strategy for the preparation of high metal loading crystalline single‐atom catalysts based on covalent organic frameworks with atomically distributed Pd ions and metal contents of up to 22.2 wt%. Theoretical simulations reveal that the crystalline framework dynamically confines Pd atoms between different binding sites ...
Kyung Seob Song   +11 more
wiley   +2 more sources

Engineering Fluoroacetate Dehalogenase by Growth‐Based Selections on Non‐Natural Organofluorides

open access: yesAngewandte Chemie, EarlyView.
We present a high‐throughput selection system to engineer fluoroacetate dehalogenases (FAcDs). By challenging E. coli populations that produce diverse FAcD libraries to grow on non‐natural organofluorides as their sole carbon source, we isolated a panel of FAcD variants with improved activity and altered substrate specificity.
Suzanne C. Jansen   +2 more
wiley   +2 more sources

Biomimetic total synthesis of ten <i>Securinega</i> alkaloids.

open access: yesOrg Chem Front
Waddell LJN   +4 more
europepmc   +1 more source

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