Results 21 to 30 of about 1,366 (154)
1,1,3-Trimethyl-3-(4-nitrophenyl)indane [PDF]
In the title compound, C(18)H(19)NO(2), the five-membered ring of the indane fragment adopts an envelope conformation, with the unsubstituted C atom, acting as the flap atom, deviating by 0.412 (3) Å from the plane through the remaining four atoms. The dihedral angle between the nitro-phenyl ring and the indane benzene ring is 72.5 (1)°.
Shi-Xu Yi +4 more
openaire +3 more sources
Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors. [PDF]
In a model Mukaiyama aldol reaction with unbiased substrates, high enantioselectivity was achieved with a modifiable bidentate iodine(I)‐based halogen bonding organocatalyst. The crucial role of halogen bonding was confirmed by the low performance of the corresponding hydrogen bond donor and via DFT calculations.
Wolf J +6 more
europepmc +2 more sources
Plant-Mediated Enantioselective Transformation of Indan-1-one and Indan-1-ol. Part 2 [PDF]
The main purpose of this publication was to obtain the S-enantiomer of indan-1-ol with high enantiomeric excess and satisfactory yield. In our research, we used carrot callus cultures (Daucus carota L.), whereby the enzymatic system reduced indan-1-one and oxidized indan-1-ol.
Wanda Mączka +3 more
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NMR analysis of (1S,1aR,6aR)-2’,3’,6,6a-tetrahydro-spiro[cycloprop[a]indene-1(1aH),1’-[1H]indene] [PDF]
The aldol condensation product of 1H-indan-1-one, (2E)-2-(2,3-dihydro-1H-inden-1-ylidene)-2,3-dihydro-1H-inden-1-one, subjected to Huang–Minlon reduction conditions was shown, via 1D and 2DNMRanalysis, to be amixture of (1S,1aR,6aR)-2’,3’,6,6a-tetrahydro-
PETER SPITELLER +2 more
doaj +3 more sources
Intramolekulare Acylgruppenwanderung O-acylierter 1,3-Diketone
At room temperature both Z-isomers of O-acylated 1-acetyl-indan-2-ones are rapidly converted into each other by a thermal intramolecular 1,5-acyl shift.
Klaus Hartke +2 more
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EARTHQUAKE VULNERABILITY ASSESSMENT (EVAS): ANALYSIS OF ENVIRONMENTAL VULNERABILITY AND SOCIAL VULNERABILITY IN RANAU AREA, SABAH, MALAYSIA [PDF]
Earthquakes are one of the most common and widely distributed natural risks to life and property. There is a need to identify the possible risk by assessing the vulnerability of the research area. The topic on Earthquake Vulnerability Assessment (EVAs)
Elystarina Indan +3 more
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An efficient methodology has been developed for synthesizing 3-(hetero)aryl/alkyl-indan-1-ones, which are highly valued scaffolds in chemistry. This method allows the mono(hetero)arylation/alkylation of indane-1,3-diones with (hetero)aryl/alkyl boronic ...
Mohammad Junaid +2 more
doaj +1 more source
4′-(4-Fluorophenyl)-1′-methyldispiro[indane-2,2′-pyrrolidine-3′,2′′-indane]-1,3,1′′-trione methanol hemisolvate [PDF]
La unidad asimétrica del compuesto del título, C29H24FNO5·0.5CH3OH, contiene dos mol-éculas independientes y una mol-ecula de disolvente de metanol. El mol-ecule de metanol es hidrógeno O-H O unido a uno de los mol-ecules independientes. Los anillos de pirrolidina en ambos mol-éculas adoptan conformaciones de media silla, mientras que los anillos de ...
Mohamed Ashraf Ali +4 more
openaire +2 more sources
Coarctate reactions are defined as reactions that include atoms at which two bonds are made and two bonds are broken simultaneously. In the pursuit of the discovery of new coarctate reactions we investigate the fragmentation reactions of cyclic ketals ...
Götz Bucher +2 more
doaj +1 more source
New fused pyrazolo[4,3-e]pyridines were obtained by multi-component reaction of 1,3-dimethyl-1H-pyrazol-5-amine or 3-phenyl-1H-pyrazol-5-amine, aromatic aldehydes and indan-1,3-dione in the presence of camphor-10-sulfonic acid (CSA) as an effective ...
Emel PELIT
doaj +1 more source

