Results 291 to 300 of about 200,870 (399)

β‐Quaternary α‐Amino Acids via Iridium‐Catalyzed Branched and Enantioselective Hydroalkylation of 1,1‐Disubstituted Styrenes

open access: yesAngewandte Chemie International Edition, Accepted Article.
A cationic Ir(I)‐complex modified with the chiral diphosphine DM‐SEGPHOS mediates the hydroalkylation of diverse α‐methyl styrenes with N‐aryl glycine derivatives. The processes occur with complete branched selectivity and high enantioselectivity. Styrenes possessing higher α‐alkyl substituents also participate to provide the targets with moderate to ...
Fenglin Hong   +4 more
wiley   +1 more source

Ruthenium Catalyzed ortho‐Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts

open access: yesAngewandte Chemie International Edition, Accepted Article.
Arylthianthrenium salts have become key intermediates for late‐stage functionalizations of drug‐like molecules. Ruthenium‐phosphine catalysts are now shown to enable their use as aryl sources in high‐yielding ortho‐C–H arylations of benzoic acids. The arylthianthrenium salts are converted chemo‐selectively, leaving aryl halides and boronates untouched.
Kaiping Wang   +9 more
wiley   +1 more source

Enterobactin inhibits microbiota-dependent activation of AhR to promote bacterial sepsis in mice. [PDF]

open access: yesNat Microbiol
Keskey RC   +18 more
europepmc   +1 more source

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