Results 151 to 160 of about 94,457 (311)

Leaftronics: Bio‐Fractal Scaffolds From Leaf Venation for Low‐Waste Electronics

open access: yesAdvanced Materials, EarlyView.
“Leaftronics” transforms naturally evolved leaf venation into quasi‐fractal scaffolds for sustainable electronics. Polymer‐infiltrated leaf skeletons can be used to fabricate ultra‐smooth, reflow‐ and thin‐film‐compatible decomposable substrates, while making the same lignocellulose networks conducting results in flexible transparent electrodes.
Rakesh Rajendran Nair   +3 more
wiley   +1 more source

A new approach to the theoretical estimation of inductive constants [PDF]

open access: yes, 1998
A new model of the inductive effect is proposed, allowing highly accurate theoretical calculations of inductive constants for a diversity of substituents, using a simple and readily available system of mathematics.
Galkin V., Cherkasov A., Cherkasov R.
core  

Unveiling Exsolution‐Induced Giant Electronic and Magnetic Property Changes in Non‐Stoichiometric Titanate Perovskite Thin Films

open access: yesAdvanced Materials, EarlyView.
A giant insulator to metal transition and emergent superparamagnetism are revealed by nanoparticle exsolution in non‐stoichiometric titanate perovskite thin films. By combining transport, synchrotron spectroscopy, and first‐principles calculations, this work reveals how defect reconfiguration and lattice reconstruction fundamentally reshape electronic ...
Sungil Kim   +11 more
wiley   +1 more source

Theory Guided Fine‐Tune of Strain Effects in Pt Ternary Alloy via Rare Earth Templating: Achieving High Performance PEMFCs Catalysts

open access: yesAdvanced Materials, EarlyView.
Theory‐guided strain engineering and rare‐earth templating are combined to create Pt5(Ce)Co@Pt multilayer nanoparticles with a Pt5Co‐like sublayer that fine‐tunes *OH binding near the ORR volcano optimum. The resulting catalyst delivers exceptional mass activity and remarkable long‐term PEMFC durability, revealing a strategy for designing highly active
Qi Zhang   +15 more
wiley   +1 more source

Application of a model of inductive effect for analysis of the reactivity of organoelement compounds

open access: yes, 2020
Abundant published evidence is presented to show the practical utility of the previously developed model of inductive effect for analysis of the reactivity of organic and organoelement compounds. The universal character and high precision of the approach
Galkin V.   +3 more
core  

Laplace‐Pressure‐Stabilized Rutile Solid‐Solution Catalysts for Acidic Water Oxidation: Enabling DSA‐Inspired Compositions

open access: yesAdvanced Materials, EarlyView.
The miscibility of foreign elements in rutile‐type IrO2 and SnO2 is greatly enhanced under high Laplace pressure, where their crystal size is reduced to the nanoscale. This enhancement leads to the successful synthesis of DSA‐composition solid‐solution nanocatalysts with notable durability during the acidic OER in water electrolysis.
Chang Hyun Park   +7 more
wiley   +1 more source

Simultaneously Engineering the Amorphous Phase and Branch Morphology of High‐Entropy Alloy Nanomaterials for Enhanced Ethylene Glycol Oxidation

open access: yesAdvanced Materials, EarlyView.
Amorphous PdCuNiCoFe high‐entropy alloy nanobranches were developed through a versatile wet‐chemical synthetic strategy enabling simultaneous control of composition, phase, and morphology. The resulting amorphous PdCuNiCoFe nanobranches exhibit outstanding electrocatalytic performances for ethylene glycol oxidation (EGOR), delivering high selectivity ...
Biao Huang   +11 more
wiley   +1 more source

A new approach to the theoretical estimation of inductive constants

open access: yes, 2020
A new model of the inductive effect is proposed, allowing highly accurate theoretical calculations of inductive constants for a diversity of substituents, using a simple and readily available system of mathematics.
Galkin V., Cherkasov A., Cherkasov R.
core  

Targeted Modulation of d‐Band Center in MoS2 Interlayer With n‐Type Co/Fe Dopants Accelerating Sulfur Reaction Kinetics in Lithium‐Sulfur Batteries

open access: yesAdvanced Materials, EarlyView.
A targeted modulation of the MoS2 electronic structure is achieved via substitutional n‐type Co/Fe co‐doping. This strategy triggers S‐mediated d‐p hybridization, optimizing the binding affinity with polysulfides to establish a volcano‐shaped relationship between the d‐band center and catalytic activity.
Junhyuk Ji   +6 more
wiley   +1 more source

Suppressing Surface Degradation in Na‐Rich Prussian Blue Cathodes via Liquid‐Phase Dehydration

open access: yesAdvanced Materials, EarlyView.
Gas bubbling in a liquid medium lowers the local water vapor pressure and continuously removes desorbed water, enabling effective dehydration of Prussian Blue without inducing surface oxidation. This interfacial mass transfer‐driven process stabilizes the surface chemistry and improves electrochemical performance, providing a strategy for handling ...
Seunghye Jang   +8 more
wiley   +1 more source

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