Results 21 to 30 of about 14,180,462 (265)

Synthesis, Structure and Photoluminescence Properties of Cd and Cd-Ln Pentafluorobenzoates with 2,2′:6′,2′-Terpyridine Derivatives

open access: yesInorganics, 2022
Six new complexes [Cd(tpy)(pfb)2] (1, tpy = 2,2′:6′,2″-terpyridine), [Ln2Cd2(tpy)2(pfb)10] (Ln = Eu (2Eu), Tb (2Tb)), [Ln2Cd2(tbtpy)2(pfb)10]·2MeCN (Ln = Eu (3Eu), Tb (3Tb), tbtpy = 4,4′,4″-tri-tert-butyl-2,2′:6′,2″-terpyridine), [Eu2Cd2(tppz)(pfb)10]n ...
Maxim A. Shmelev   +8 more
doaj   +1 more source

Synthesis and X-ray Diffraction of Cyclopalladated Compounds Derived from Imine Ligands

open access: yesChemistry Proceedings, 2022
The crystal structures of mononuclear cyclopalladated compounds with phosphine ligands are investigated. The reactions of the five-membered cyclopalladated dinuclear complexes [Pd(L)(µ-Cl)]2 with the monophosphine ligand (PPh3) and diphosphine ligand ...
Basma Al Janabi   +2 more
doaj   +1 more source

One-Pot Thermal Synthesis of g-C3N4/ZnO Composites for the Degradation of 5-Fluoruracil Cytostatic Drug under UV-LED Irradiation

open access: yesNanomaterials, 2022
Graphitic carbon nitride (g-C3N4) was used to enhance the photocatalytic activity of ZnO nanoparticles for the degradation of 5-fluorouracil (5-FU) cytostatic drug under UV-LED irradiation.
Álvaro Pérez-Molina   +4 more
doaj   +1 more source

Synthesis of porous inorganic hollow fibers without harmful solvents [PDF]

open access: yes, 2015
A route for the fabrication of porous inorganic hollow fibers with high surface-area-to-volume ratio that avoids harmful solvents is presented. The approach is based on bio-ionic gelation of an aqueous mixture of inorganic particles and sodium alginate ...
Benes, Nieck E.   +6 more
core   +2 more sources

Electrodes Based on Carbon Aerogels Partially Graphitized by Doping with Transition Metals for Oxygen Reduction Reaction

open access: yesNanomaterials, 2018
A series of carbon aerogels doped with iron, cobalt and nickel have been prepared. Metal nanoparticles very well dispersed into the carbon matrix catalyze the formation of graphitic clusters around them.
Abdalla Abdelwahab   +6 more
doaj   +1 more source

Palladacycles as Functionalized Metal-Ligand Precursors, Contain Tridentate [Csp2, N, S] Ligands

open access: yesChemistry Proceedings, 2021
The reactivity of R–CH=N–(C6H4–2–SMe) with R = 4–Br–C6H5, R = 3–Br–C6H5, R = 2–Cl–C6H5 with palladium (II) salts was investigated in this study. We were able to prepare and characterize the cyclometallation complexes.
Basma Al Janabi   +2 more
doaj   +1 more source

Study on the Effect of the Ligand Structure in Palladium Organometallic Catalysts in the Suzuki–Miyaura Cross-Coupling Reaction

open access: yesChemistry Proceedings, 2021
In this communication, we present the results obtained using a family of cyclometallated palladium compounds as catalysts for the Suzuki–Miyaura cross-coupling reaction between an aryl halide and phenylboronic acid. We have studied the structural factors
Paula Munín-Cruz   +4 more
doaj   +1 more source

Organometallic half-sandwich iridium anticancer complexes [PDF]

open access: yes, 2011
The low-spin 5d6 IrIII organometallic half-sandwich complexes [(η5-Cpx)Ir(XY)Cl]0/+, Cpx = Cp*, tetramethyl(phenyl)cyclopentadienyl (Cpxph), or tetramethyl(biphenyl)cyclopentadienyl (Cpxbiph), XY = 1,10-phenanthroline (4−6), 2,2′-bipyridine (7−9 ...
Liu, Zhe   +34 more
core   +2 more sources

Structural design and particle size examination on NiO-CeO2 catalysts supported on 3D-printed carbon monoliths for CO2 methanation

open access: yesJournal of CO2 Utilization
3D-printed high-surface carbon monoliths have been fabricated and tested as catalyst supports of CO2 methanation active phases (NiO-CeO2, 12 wt% Ni). The carbon carriers show a developed microporosity and good adherence to the catalytic phases of NiO ...
Iván Martínez-López   +7 more
doaj   +1 more source

Efficient and selective chemical transformations under flow conditions: The combination of supported catalysts and supercritical fluids

open access: yesBeilstein Journal of Organic Chemistry, 2011
This paper reviews the current trends in the combined use of supported catalytic systems, either on solid supports or in liquid phases and supercritical fluids (scFs), to develop selective and enantioselective chemical transformations under continuous ...
M. Isabel Burguete   +2 more
doaj   +1 more source

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