Results 191 to 200 of about 7,266 (261)

Linear Pentanuclear 3d–4f M‐Gd‐M‐Gd‐M Complexes Prepared From a One‐Pot Reaction Show Intramolecular Ferromagnetic Interactions (M  =  Cu, Ni, and Co)

European Journal of Inorganic Chemistry, EarlyView.
Using a multidentate ligand with two distinct coordination sites and a bridging coordination site, a series of novel linear pentanuclear complexes with alternately arranged 3d and 4f ions via a one‐pot reaction were synthesized. Cryomagnetic studies revealed the presence of intramolecular ferromagnetic interactions and their magnetic entropy changes ...
Takuya Shiga, Yukiko Okamoto, Nozomi Mihara, Masayuki Nihei   +3 more
wiley   +1 more source

Confinement Effects in High‑Efficiency Electrocatalysis: Design, Mechanisms, and Applications

Interdisciplinary Materials, EarlyView.
Confinement has emerged as a powerful strategy in electrocatalysis and has been widely employed to enhance catalytic performance. This review summarizes recent advances in confined electrocatalysis, encompassing the design of confined electrocatalysts, mechanistic insights into confinement effects, and representative applications across diverse zero ...
Congcong Yang, Zhihang Liu, Jingshuo Liu, Chuang Chen, Zhiqun Lin, Likun Gao   +5 more
wiley   +1 more source

Intelligent design of artificial biocatalyst for biomedical diseases

Journal of Intelligent Medicine, EarlyView.
This review summarizes recent advances in the intelligent design of artificial biocatalysts for biomedical diseases. By leveraging tailored design strategies, including environment‐responsive engineering and rational/artificial intelligence‐aided optimization, these biocatalysts enable precise modulation of pathological microenvironments and targeted ...
Lijie Zhang, Nan Song, Huanhuan Qiao, Si Sun   +3 more
wiley   +1 more source

Experimental and Comparative Study of the Corrosion Behavior of Lean Duplex Stainless Steel in Seawater

Materials and Corrosion, EarlyView.
The localized corrosion behavior of lean duplex stainless steel EN 1.4062 is systematically compared with austenitic and higher‐alloyed duplex grades in natural seawater. A clear resistance ranking is established, highlighting EN 1.4062 as a cost‐effective alternative for limited marine exposure.
Mohammad Hassanzadeh, Nicolas Larché, Audrey Allion‐Maurer, Raf Dewil, Barbara Rossi   +4 more
wiley   +1 more source

Simultaneous Electrochemical and Inductively Coupled Plasma Optical Emission Spectroscopy Measurements on AA 7075

Materials and Corrosion, EarlyView.
Schematic representation of the operando ICP‐OES setup during the electrochemical experiment (left). Resulting plot showing the dissolution of the individual alloy components of AA7075 as a function of applied potential in 10 mM NaCl (right). ABSTRACT This publication deals with the simultaneous acquisition of electrochemical and inductively coupled ...
Claudia Kutzer‐Schulze, Michael Schneider, Alexander Michaelis   +2 more
wiley   +1 more source

Corrosion Behavior of Commercial FeCrAl and TiAl Alloys in Molten Pb With 2E‐7 wt% Oxygen at 600°C and 700°C

Materials and Corrosion, EarlyView.
Excellent corrosion resistance of commercial Al‐containing materials is shown for exposures to liquid lead (Pb) at 600°C. However, oxide scale failure occurs at 700°C. The formed oxide scales and their failure mechanisms are explored. ABSTRACT Liquid lead (Pb) is an attractive heat transfer fluid for advanced thermal energy storage (TES) systems.
Renate Fetzer, Anisa Purwitasari, Annette Heinzel, Alfons Weisenburger, Georg Müller   +4 more
wiley   +1 more source

Analysis of Corrosion and Wall Perforation in the Heat Exchanger Made of AISI 316L Stainless Steel

Materials and Corrosion, EarlyView.
Elevated passivation temperature is identified as the dominant factor triggering localized corrosion and subsequent perforation of AISI 316L heat exchanger tubes. Electrochemical and complementary characterization results show that the alloy retains high resistance to general, pitting, and intergranular corrosion, indicating that failure primarily ...
Bojana Radojković, Bore Jegdić, Branimir Grgur, Stefan Dikić, Jovanka Pejić, Anđela Simović, Nataša Gajić, Aleksandra Popović   +7 more
wiley   +1 more source

Multi‐Method Investigation of Intergranular Corrosion of the Aluminium Alloy EN AW‐2024 With Different Cooling Rates After Solution Heat Treatment—Metallography and Eddy Current Testing

Materials and Corrosion, EarlyView.
The corrosion resistance of heat‐treatable aluminium alloys depends directly on the applied heat treatment. This article discusses the relationship between cooling rate and intergranular corrosion sensitivity. The intergranular corrosion depths were determined by light microscopy of cross‐sections and correlated with both non‐destructive eddy current ...
Hanna Schulz, Andreas Heyn, Saskia Roßberg, Paul Rosemann   +3 more
wiley   +1 more source

Machine learning‐driven advances in carbon‐based quantum dots: Opportunities accompanied by challenges

Responsive Materials, EarlyView.
Machine learning provides a unifying framework to connect structure, fluorescence properties, and applications of carbon‐based quantum dots. This review highlights how data‐driven strategies enable fluorescence regulation, reveal underlying mechanisms, and accelerate the rational design of functional carbon dots.
Liangfeng Chen, Siwei Yang, Xiangqian Cui, Ziheng Liu, Hang Wang, Yongqiang Li, Peng He, Miao Wang, Guqiao Ding   +8 more
wiley   +1 more source

Effect of Metal–Metal Distance on the Performance of Dual‐Atom Catalysts for the Oxygen Reduction Reaction: A Density Functional Theory and Micro‐kinetics Study

Small, EarlyView.
Density functional theory calculations and microkinetic modeling were carried out on 108 dual‐atom catalysts with varied metalmetal distances ranging from 2.2 to 3.5 Å. The results reveal that moderate spacing of around 3.0 Å promotes bridging oxygen adsorption and dissociative reduction pathways, weakens the hydroxylhydroperoxyl scaling relationship ...
Yu Mao, Yongfang Zhou, Mengjiao Li, Ziyun Wang, Run Shi, Lu Shang, Tierui Zhang, Geoffrey I. N. Waterhouse   +7 more
wiley   +1 more source