Results 61 to 70 of about 36,750 (220)

Tautomerization Kinetics of Thiouracils at Low Temperatures Driven Solely by Quantum‐Mechanical Tunnelling: Predictions of Suitable Candidates for Future Experiments

open access: yesInternational Journal of Chemical Kinetics, Volume 58, Issue 6, Page 269-277, June 2026.
ABSTRACT In the past two decades numerous experiments have been conducted on the kinetics of reactions occurring at low temperatures on inert matrices. In particular, unimolecular proton‐transfer photo‐reactions of compounds containing a carbon–sulfur double bond, or thione group C═S, can lead to the formation of higher energy isomers or tautomers with
Judith Wurmel, John M. Simmie
wiley   +1 more source

Interstellar abundances : gas and dust.

open access: yesThe Astrophysical Journal, 1974
Data on abundances of interstellar atoms, ions and molecules in front of zeta Oph are assembled and analyzed. The gas-phase abundances of at least 11 heavy elements are significantly lower, relative to hydrogen, than in the solar system. The abundance deficiencies of certain elements correlate with the temperatures derived theoretically for particle ...
openaire   +1 more source

Combustion and Pyrolysis EA‐IRMS Techniques to Determine the δ2H of Diamonds

open access: yesRapid Communications in Mass Spectrometry, Volume 40, Issue 10, 30 May 2026.
ABSTRACT Rationale Diamonds are generally considered to be metasomatic minerals originating from the Earth's mantle. They formed through the interaction of carbon‐bearing fluids or melts with the surrounding deep lithology. Most knowledge about the formation of diamonds comes from studying their mineral inclusions or stable isotopes.
François Fourel   +4 more
wiley   +1 more source

The Infrared Complex Refractive Index and Band Strengths of Coronene Thin Films

open access: yesThe Astrophysical Journal
Polycyclic aromatic hydrocarbon (PAH) molecules have long been theorized to be present in a multitude of interstellar environments. The radio-frequency detections of specific cyanosubstituted PAH molecules in the Taurus Molecular Cloud have provided new ...
J. E. Roser, L. Jovanović, A. Ricca
doaj   +1 more source

Strongly Depleted Methanol and Hypervolatiles in Comet C/2021 A1 (Leonard): Signatures of Interstellar Chemistry?

open access: yesThe Planetary Science Journal, 2023
We measured the chemical composition of comet C/2021 A1 (Leonard) using the long-slit echelle grating spectrograph iSHELL/IRTF on 2021 December 20 and on 2022 January 8 and 9.
Sara Faggi   +3 more
doaj   +1 more source

Abundances and Depletions of Interstellar Oxygen [PDF]

open access: yesThe Astrophysical Journal, 2005
62 total pages (37 text), 15 figures, 9 ...
Jensen, Adam G.   +2 more
openaire   +2 more sources

Modelling the nebular emission from primeval to present-day star-forming galaxies [PDF]

open access: yes, 2016
We present a new model of the nebular emission from star-forming galaxies in a wide range of chemical compositions, appropriate to interpret observations of galaxies at all cosmic epochs.
Bruzual, Gustavo   +2 more
core   +3 more sources

From the Modeling of Experiments to the Ab Initio Prediction of Rate Constants: Statistical Rate Theory for a Quantitative Understanding of Gas‐Phase Ion Chemistry

open access: yesChemPhysChem, Volume 27, Issue 8, 28 April 2026.
For directly comparing experimental results on gas‐phase ion reactions with the predictions from quantum chemical calculations, the latter must first be converted into rate constants. This review addresses the question of whether current methods of statistical rate theory can accomplish this task reliably. Statistical rate theory has long been used for
Thomas Auth, Konrad Koszinowski
wiley   +1 more source

Features of Chemical-Element Abundances in Open Star Clusters of the Galaxy

open access: yesOpen Astronomy, 2016
On the basis of the authors’ compiled catalog containing spectroscopic abundances of 14 chemical elements for 90 open star clusters of the Galaxy, we show that in the young clusters not only barium but also three other studied elements of slow neutron ...
Marsakov V. A.   +3 more
doaj   +1 more source

The Abundance of Interstellar Boron

open access: yesThe Astrophysical Journal, 2000
Accepted for publication in The Astrophysical Journal. 13 pages, including 2 tables and 4 figures. Also available at http://fuse.pha.jhu.edu/~howk/Papers/
Howk, J. Christopher   +2 more
openaire   +2 more sources

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